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BITS AND BLOBS AND UFOS
                                          A hazy problem in need of a clearer solution
                         Bits and Blobs



                                    and UFOs









                         A HAZY PROBLEM IN NEED OF

                                   A CLEARER SOLUTION




                           W R IT TEN  A ND  PHO T O S  PR O VI DED  B Y  G A R Y  S PEDDI NG ,  PH . D .




        Over time many alcoholic            ver the past two decades we have been   later); in essence, you can be a puritan or live
        beverages are likely to form a   O presented  with  an  ever-increasing  with these messes! But your customer might
                                        number of spirit samples with hauntingly   not forgive you.
        haze, show a light precipitate,   eerie-looking sediments, precipitates, gels,   The topic of precipitations and hazes (aka.
        or even exhibit a potential for   and globs of unidentified (and sometimes   turbidity) in distilled spirits is quite complex
        significant turbidity which can   unidentifiable) matter. The situation is getting   and  has  not  been  discussed  much  in  the
        be caused by colloidally dissolved   worse as more craft products enter into the   literature since a seminal series of papers
        organic substances or inorganic   marketplace and, furthermore, the extent of   published in 1960 and 1963 (Warwicker,
                                        matter appearing in solution is increasing to
                                                                                1960; 1963 a, b). Primarily the topic has not
        metal or mineral deposition.    the point that sometimes the entire bottle   received much attention in the public domain
        Significantly, sediments and    appears like a snow-globe ornament, much   (journal publications), probably because most
        hazes are on the rise in craft-  like the beer colloidal mess shown in the figure   distilleries privately cured this issue with use of
        distilled spirits. Such issues cause   below. A lesser cluttered example of a floc in a   completely pure dilution water, free of mineral
        alarm for distillers unaware as   bottle of a white spirit is also shown.  ions, or via chill proofing and filtration with
                                         The urgent calls received are requests for us   clearly defined specifications as to mineral
        to their origins or how to prevent   to indicate to the distiller (as for the brewer) how   content in the filter media, these being key
        or alleviate their formation. We   to resolve the issue. There are two problems to   processes for long(er)-term clarity/stability.
        will thus discuss the origins of   this, one being the time and expense needed   However, hazes/turbidity include those
        these unsightly issues and discuss   to  try  and  pinpoint  the  compositional  nature   formed  by  organic  and  inorganic  types  of
                                        of said UFOs (Unidentified floating objects),   matter. We recently uncovered some unique
        colloidal stability of beverages.   unless it is one of two key causes (see below).   components leading to precipitates/suspended
        To do this we need to dip into   New causes of hazes are being discovered with   solids, possibly based on plasticizers or glass
        the Scotch whisky literature    our application of newer technologies. The   production chemistries (glass-mold release
        and reach back to the 1960’s    second problem is that when we tell the distiller   components  or  oils  or  coatings,  etc.,  used
        for some cogent discussions,    how to possibly resolve it they categorically   in  plastic  tubing/containers).  Near  infrared
        and even much earlier. Even     state that the suggested solution is a non-  microscopy is becoming a useful, though
                                        starter (again for reasons as will be explained   expensive, technique in uncovering the culprits
        then we will see that there are                                         involved  in  these  more  unusual  cases  and
        still unknowns out there with    Beer Colloidal Haze                    may  become  the  tool  of  choice  in  advancing
        room for speculations about                                             our understanding in this area. Though, at
        Unidentified Floating Objects
        (UFOs) in different kinds of                                             Floc Haze
        distilled spirits. Let’s try to
        clear the muddy waters or the
        “greying” spirits — read on.

        92                                                                                      WWW.ARTISANSPIRITMAG.COM
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