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International Conference on

                                  Recent Trends in Environmental Sustainability


                                                    ESCON22/NMsB/11
               Effective sequestration of cresol red dye from wastewater with corn leaves biomass and
               its nanocomposites with zinc oxide and magnetite

                                                                                                        1
                                                                1
                                  1*
                                                                                      1,
               Muhammad  Imran ,  Muhammad  Mohsin  Iqbal ,  Muhammad  Amjad Behzad  Murtaza ,
                                      1
               Muhammad Asif Naeem
               1 Department of Environmental Sciences, COMSATS University Islamabad, Vehari- Campus,
               61100 Pakistan
               Correspondence: imranrb@cuivehari.edu.pk
               Abstract
               Water is a basic need for all the living organisms to sustain life. United Nations estimates show
               that about 800 million people have not access to clean water and this population is increasing
               continuously. Water contamination with dye is a problem of high concern for the environment
               and human health. In the textile industries, Cresol red dye (CR) is commonly used for the
               nylon,  cotton  silk,  polyacrylonitrile  and  wool.  The  dyes  are  very  problematic  due  to  their
               complex structure and hence it’s very important to remediate dyes contaminated water. Current
               study  is  designed  to  assess  the  adsorption  potential  of  Corn  leaves  (CL)  and  its  nano
               nanocomposites with zinc oxide (CL/ZnO) and magnetite nanoparticles (CL/MNPs) for batch
               scale removal of CR. To obtain the objectives, the impact of different process parameters i.e.,
               adsorbent dose (1 – 4 g/L), initial CR concentration (25 - 200 mg/L), pH (2 - 8), and contact
               time (0 - 180 min) was evaluated. The revealed CR removal by CL, CL/ZnO, and CL/MNPs
               was 65.3-50.8%, 71.6-56.8%, and 51.2-42.2%, respectively when the initial level of CR was
               varied from 25-200 mg/L. However, the removal CR removal changed from 38.6-60.8%, 50.8-
               63.9%,  and  36.5-50.0%  with  Cl,  CL/ZnO,  and  CL/MNPs,  respectively  when  dosage  was
               changed 1-4 g/L. Freundlich model best represented the experimental adsorption at equilibrium
                                                                                nd
               while the kinetic experimental adsorption well fitted with pseudo 2  order kinetic model. The
               comparison of the adsorbents used in the present study for CR removal with literature shows
               that the proposed materials are more efficient with greater adsorption capacity. Hence, it is
               suggested that the composites of nanoparticles should be used for the remediation of CR and
               other dyes.
               Keywords: CR dye; composites; adsorbents; removal




























                 Department of Environmental Sciences, COMSATS University Islamabad, Vehari Campus

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