Page 31 - Practical-workbook-organic-3
P. 31

8.  Calculate the needed amounts to do the reaction (in gram for solid & ml for

             liquid) of 0.04 mole of hydrazine hydrate and 0.04 mole of ethyl acetoacetate, then
             calculate the theoretical yield.
                  (M.Wt. of hydrazine hydrate = 50 g &    = 1.032 g/ml)

                  (M.Wt. of ethyl acetoacetate = 132.14 g &    = 1.02 g/ml)
                   (M.Wt. of 3-methyl-pyrazolinone = 98.11 g)


             Hydrazine hydrate                Ethyl acetoacetate                 Theoretical yield
                 amount (ml)                     amount (ml)

         ……………………….…                      ………………………...                   ……………………….……….
         …………………….……                      ……………………….…. ..…………..……………….…
         ………………….………                      .…………………….…..                  ….………………….…………

         …………………………… …………………….……. …...…………………………
         …………………………… ………………….………                                         ………………………………
         …………………………… …….……………………                                         ………………………………

         …………………………… ……...……….…………                                       …..….…….…………………
         ………………….………                      ……….…….…………… ………………………………
         …………………………… ……..…….……………                                        ………………………………

         …………………………… ……….….……………… ………………………………
         ………………………..…                     ………….........................  ………………………………



        9.   In the previous example, if the weight of the pure dry powder 3-methyl-
            pyrazolinone was 1.95 gram, calculate the %yield.
            ……………………………………………………………………………………………

            ……………………………………………………………………………………………
            ……………………………………………………………………………………………

            …………………………………………………..……………………………………..…
            …………………………………………………………………………………………...























                                                                                                        31
   26   27   28   29   30   31   32   33   34   35   36