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Rutherford’s atomic model

                         Atom is composed of a positively
                  charged     nucleus    surrounded      by
                   negatively  charged  electrons,  just  like
                  planets revolving around the sun. Most of

                  the mass in an atom is concentrated in the
                 nucleus and a large fraction of its volume
                  is empty space. As an atom is neutral, the

                  numbers  of  the  positive  charges  in  the
                  nucleus (the number of  protons) must be
                  the same as that of electrons.

                                                                         Figure 8. Rutherford’s Atomic Theory


                Bohr’s Atomic Theory


                    In  1913,  Bohr  applied  Placnk‟s  quantum  theory  to  put  formward  his  postulate  so  as  to
                explain the atomic stability and the hydrogen atomic spectrum.

                    Bohr’s Postulates
                a. Electrons  travel  around  the  nucleus  in  a  certain  stationary

                  course  called  an  orbit  or  a  shell.  Athough  electrons  experience

                  acceleration,  they  do  not  emit  or  absorb  energy  in  the  orbit,  hece
                  their energy remains constant.

                b.Electrons  can  move  from  one  orbit  to  another  by  emitting  or
                  absorbing energy.

                 In general, the Bohr‟s atomic model could explain the atomic stability

                and the hydrogen atomic spectrum well. However, it had weaknesses
                                                                                            Figure 9. Niels Bohr
                among them:

                -  The model could only explain the hydrogen atomic spectrum
                 accurately, and failed to explain atomic spectra that were more

                 complex than those of hydrogen.

                -  The assumption that electrons travel around the nucleus in a
                 circular orbit was  not  completely true, for ellipse shapes  are

                 possible.
                -  The  model  cannot  explain  the  thin  lines  in  the  hydrogen

                 atomic  spectrum  because  Bohr  only  considers  electron  as    Figure 10. Bohr’s Atomic Theory
                 particles.  The  next  atomic  theory  uses  the  dualism

                 characteristic of electron, i.e. electron as a particle and a wave. The characteristic causes the

                 position of the electrons inside an atom to be indeterminate and can only be described by a
                 probability.



               Chemistry_grade_X                                                                            7
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