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Clinical pharmacy PharmD program                     Third level                          Phytochemistry-1 (PG-504)


                           O                     CHO            CHO                  O









                            CH OH                CH OH          CH OH                CH OH
                                                    2
                                                                                        2
                                                                  2
                              2
                          Richstein Formula                                    Richstein Formula
                                   D-Glucose                           L-Glucose
              Diastereoisomers: Sugar pair which is not mirror images, and differ widely in

              both physical and chemical properties and given different names, e.g. D-allose

              and D-mannose.


              Epimers:  two  diastereoisomers,  differ  only  in  the  configuration  of  a  single

              asymmetric center.



                      CHO                   CHO                    CHO                    CHO









                      CH OH                 CH OH                  CH OH                  CH OH
                                                                      2
                                               2
                        2
                                                                                             2
                   D-Glucose              L-Glucose              D-Allose               D-Mannose
                           Enantiomers                                   Diastereoisomers

                     CHO                    CHO                    CHO                    CHO









                     CH OH                  CH OH                  CH OH                  CH OH
                                                                      2
                        2
                                              2
                                                                                             2
                   D-Glucose              D-Mannose              D-Glucose              D-Galactose
                              Epimers                                      4-Epimers









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