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The Chemistry and Fertility of Soils under Tropical Weeds   113



                           researchers  report  that  the  release  of  K  and  other  nutrient  elements  from  soil
                           mineral increases with the decrease in soil pH (Salam, 1989).  This suggests that any
                           chemical reactions that may decrease the soil pH may in turn drive the detachment
                           of K from soil minerals.  The chemical reactions may be naturally driven like root
                           excretion  and  antropogenically  origin  like  soil  contamination  by  acid  industrial
                           waste.
                              Root excretion may also enhance the organic matter decomposition through
                           the  soil  enzymatic  reactions.    Various  soil  enzymes  produced  by  roots  and  by
                           microorganisms  and  macroorganisms  associated  with  root  existence,  like
                           phosphatases, arylsulfatases, and proteases, may speed up the decays of organic
                           matters  containing  the  functional  K.    The  amounts  of  soil  enzymes  produced  by
                           these  living  things  may  determine  the  amount  of  K  released  into  the  soil
                           environment.  Any factors that may support these living things may enhance the
                           increase in soil enzymatic activities and the release of K into the soil environment.
                                                                                          +
                              The  enhancement  of  K  released  by  the  root-related  production  of  H   and
                           enzymes is expressed in the increase in dissolved K and exchangeable K.  Salam et
                           al.  (2019)  report  that  the  enhancement  of  exchangeable  K  by  weed  presence  is
                           related to the characteristics of weeds, among which is the Root-To-Shoot Ratio
                           (RST). Weeds with high RST like Arachis pintoi may drive more intensive release of
                           K from K-sources in the soil environment (Ontia, 2018; Salam et al., 2019).



                           7.1  The Release of Potassium from Soil Minerals


                              Potassium in soils is contained in mineral and organic matters, which are not
                           easily available to plant root absorption.  Some of K reserves  in soil are listed in
                           Table  7.1,  which  mainly  exist  as  silicate  minerals,  like  feldspars,  and  organic
                                                                         +
                           matters.    Potassium  is  absorbed  by  plant  roots  as  K   ions  and  therefore  the
                                                                         +
                           structural K in the silicate minerals must be released as K  to be available to plants.
                                                 +
                           The mechanism by which K  ions are released into the soil solution from mineral K
                           is called dissolution or chemical weathering.  Similarly, organic K must be released
                              +
                           as K  into the soil solution through a chemical mechanism called decomposition.
                           Therefore, the soil K in the soil environment is not only supplied by mineral sources
                           but also by organic sources.  The root excretion may enhance the soil available K
                           from soil minerals particularly in young soils with enough K-minerals and from soil
                           organic  matters  containing  K.  Inputs  of  organic  matters  into  soils  from  root
                                                          Abdul Kadir Salam and Nanik Sriyani  – 2019
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