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156   The Chemistry and Fertility of Soils under Tropical Weeds



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                           of H  as a result of the reaction between CO 2  and water molecules.  The decrease in
                           soil  pH  may  release  some  nutrient  elements  contained  in  the  structure  of  the
                           primary and secondary minerals.  The complexing agents may complex parts of the
                           nutrient  elements  and  cause  the  nutrient  elements  to  stay  dissolved  in  the  soil
                           solution  and,  by  mass  action,  may  also  increase  the  release  of  plant  nutrient
                           elements from soil minerals.
                              Weed roots and microorganism and macrorganims associated with them also
                           excrete soil enzymes.  These biocatalysts are very important in the cycles of some
                           nutrient elements like C, P, N, and S.  The presence of soil enzymes may speed up
                           the transformation of organic nutrient elements, which are not available to root
                           absorption,  into  inorganic  nutrient  elements,  that  are  readily  available  to  plant
                           roots.  The presence of  soil enzymes may accelerate the supplies of nutrients to
                           plant roots from organic sources.
                              In  addition  to  their  effects  on  the  soil  chemical  and  the  soil  biological
                           properties  mentioned  above,  the  presence  of  weeds  is  also  very  important  to
                           improve  the  soil  physical  properties.    The  increase  in  organic  C  through  weed
                           residues may increase the soil organic C and the soil moisture content and maintain
                           the soil temperature.  The increase in soil CEC may also maintain the soil moisture
                           content.  The  increase  in  the  soil  organic  C  is  not  affected  only  by  weed  organic
                           residues.  The excretions of weeds roots may also increase the soil organic matter.
                           In general, the presence of weeds may improve the soil fertility.



                           10.1  The Chemistry of Soils under Weed Management

                              The effects of weeds are significant on the soil chemical properties and also on
                           the  soil  biological  and  the  soil  physical  properties.    The  soil  chemical  properties
                           affected  by  weeds  may  include  the  soil  pH,  the  soil  complexing  agents,  the  soil
                           enzymatic properties, the concentration of CO 2 , the soil organic matter, organic C
                           and  total  N,  the  soil  CEC,  the  availability  of  various  nutrient  elements,  the  soil
                           exchangeable bases, etc.  The soil biological properties affected may include the
                           population and activity of soil microorganisms, the evolution of CO 2 , the population
                           of mesoorganisms like earthworms, etc.  The soil physical properties affected may
                           include the soil moisture content and the soil temperature.
                              The soil pH in the rhizosphere of weeds decreases due to several reasons.  The
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                           first  is  the  excretion  of  H   ions  by  weed  roots.    The  second  is  the  excretion  of
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                           organic acids by weed roots.  The combined excretion of H  and organic acids by
                           Abdul Kadir Salam and Nanik Sriyani – 2019
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