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64   The Chemistry and Fertility of Soils under Tropical Weeds



                              The forest conversion was also reported to affect the shifting in the optimum
                           pH for phosphatases (Salam et al., 1998; Salam, 2014).  Optimum pH is a particular
                           pH at which the activity of phosphatase is highest. Land-use conversion from the
                           primary  forest  to  the  secondary  forest,  coffee  plantation,  and  cultivated  lands
                           shifted the optimum values for phosphatases to higher values (Fig. 4.2).  The value
                           of the optimum pH in the primary forest  was the lowest i.e  5.0 and that in the
                           coffee plantation was the highest i.e 6.3 (Salam et al., 1998b).  Geiger et al. (1998)
                           also  observed  such  phenomenon;  Cu  caused  a  shift  in  the  optimum  pH  of  -
                           glucosidase towards lower pH values.



                                           7

                                          6.5

                                           6
                                       Optimum pH   5.5

                                           5

                                          4.5

                                           4
                                          3.5
                                           3
                                                Primary  Secondary Cultivated  Coffee
                                                Forest  Forest   Land  Plantation



                                       Fig. 4.2.  The shifting of optimum pH by forest clearing and
                                             land-use conversion (Salam et al., 1998b).

                              Soil  researchers  suggest  that  soil  pH  may  greatly  affect  the  soil  enzymatic
                           activities,  particularly  more  important  for  phosphatases.  Soil  pH  determines  the
                           magnitude of their activities and types in soils (Malcolm, 1983; Nakas et al., 1987;
                           Rojo et al., 1990; Reddy et al., 1991; Trasar-Cepeda et al., 1991; Salam et al., 1998b;
                           1998e;  Sarapatka  et  al.,  2004).    Sarapatka  et  al.  (2004)  document  that  acid
                           phosphatase activity in the root zones of various species and cereal cultivars was
                           negatively  correlated  with  increasing  pH  and  available  phosphorus  level  in  the

                           Abdul Kadir Salam and Nanik Sriyani – 2019
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