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Ozone concentration (milli-Pascals)    stratosphere’s air becomes warmer with altitude, attaining a
                                                                             maximum temperature of –3°C (27°F) at its top. The reason
                               0     5    10    15   20    25    30   35
                           120                                               is that ozone and oxygen absorb and scatter the sun’s ultravi-
                                                                             olet (UV) radiation (p. 49), so that much of the UV radiation
                           110                                               that penetrates the upper stratosphere fails to reach the lower
                                                             Thermosphere    stratosphere. Most of the atmosphere’s ozone concentrates
                                                             (up to 500 km)
                           100                                               in a portion of the stratosphere roughly 17–30 km (10–19 mi)
                                                                             above sea level, a region we have come to call Earth’s ozone
                            90                                               layer. The ozone layer greatly reduces the amount of UV
                                                                             radiation that reaches Earth’s surface. Because UV light
                                         Temperature profile
                            80                                               can damage living tissue and induce mutations in DNA, the
                                                              Mesosphere     ozone layer’s protective effects are vital for life on Earth.
                            70                                                   Above the stratosphere lies the  mesosphere, which
                                                                             extends 50–80 km (31–56 mi) above sea level. Air pressure
                          Altitude (km)  50                                  tude. The thermosphere, our atmosphere’s top layer, extends
                            60
                                                                             is extremely low here, and temperatures decrease with alti-
                                                                             upward to an altitude of 500 km (300 mi).

                            40          Ozone
                                        concentration
                                                              Stratosphere   Temperature, pressure, and humidity
                            30
                                                                             vary within the atmosphere
                            20                                               Air moves dynamically within the lower atmosphere as a
                                                               Tropopause
                                                                             result of differences in the physical properties of air masses.
                            10                                               Among these properties are pressure and density, relative
                                                              Troposphere
                                                                             humidity, and temperature.
                             0                                                   Gravity pulls gas molecules toward Earth’s surface, caus-
                              -80      -60      -40       -20       0        ing air to be most dense near the surface and less dense as
                                              Temperature (ºC)
                                                                             altitude increases.  Atmospheric pressure, which measures
                        Figure 17.2 The atmosphere’s layers differ in their properties.   the  force  per  unit  area  produced  by  a  column  of  air,  also
                        Temperature (red line) drops with altitude in the troposphere, rises   decreases with altitude, because at higher altitudes there are
                        with altitude in the stratosphere, drops in the mesosphere, and rises   fewer molecules being pulled down by gravity (Figure 17.3).
                        in the thermosphere. The tropopause separates the troposphere
                        from the stratosphere. Ozone (blue-shaded area) reaches a peak in
                        the lower stratosphere, giving rise to the term ozone layer. Adapted   50
                        from Jacobson, M.Z., 2002. Atmospheric pollution: History, science, and regula-
                        tion. Cambridge: Cambridge University Press; and Parson, E.A., 2003. Protecting
                        the ozone layer: Science and strategy. Oxford: Oxford University Press.
                                                                                40
                                                                                       Weather balloon
                        diameter, like the fuzzy skin of a peach. It consists of four
                        layers that differ in temperature, density, and composition   30
                        (Figure 17.2).                                                                                            CHAPTER 17 • AT m os PHER i C   sC i E n CE , Ai R  Qu A li T y,  A nd Poll u T i on Con TR ol
                            The bottommost layer, the troposphere, blankets Earth’s   Altitude (km)  Above 90% of            Density of air molecules
                        surface  and  provides  us  the  air  we  breathe.  Movement  of    air molecules
                        air within the troposphere also drives the planet’s weather.   20
                        Although it is thin (averaging 11 km or 7 mi high) relative          Airplane
                                                                                               Mt. Everest
                        to the atmosphere’s other layers, the troposphere contains
                        three-quarters of the atmosphere’s mass, because gravity   10                Above 50% of
                                                                                                     air molecules
                        pulls mass downwards, making air denser near Earth’s sur-  5.5
                        face. Tropospheric air gets colder with altitude, dropping to
                        roughly –52°C (–62°F) at the top of the troposphere. At this   0
                        point, temperatures stabilize, marking a boundary called the   0 100  300  500  700   900
                        tropopause. The tropopause acts like a cap, limiting mixing   (low)                  (high)
                        between the troposphere and the atmospheric layer above it,    Atmospheric pressure (millibars)
                        the stratosphere.                                    Figure 17.3 As one climbs higher through the atmosphere,
                            The stratosphere extends 11–50 km (7–31 mi) above sea   gas molecules become less densely packed, and atmos-
                        level. Similar in composition to the troposphere, the strato-  pheric pressure decreases. One needs to be only 5.5 km
                        sphere is 1000 times drier and less dense. Its gases expe-  (3.4 mi) high to be above half the planet’s air molecules. Adapted
                        rience little vertical mixing, so once substances (including   from Ahrens, C.D., 2007. Meteorology today, 8th ed. Fig 1.9. © 2007. Belmont,
                        pollutants) enter it, they tend to remain for a long time. The   CA: Brooks/Cole. By permission of Cengage Learning.  469







           M17_WITH7428_05_SE_C17.indd   469                                                                                    12/12/14   3:22 PM
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