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low level of acceptance in those days.  The blend contains 40 to 60 percent  this helps in promoting a more uni-
                 However, the adhesive properties of  of ABS, while the remaining is made  form absorption during the activa-
                 plastics were enhanced through the  up of PC. This mixture offers high duc-  tion stage.
                 implementation of a chromic acid-  tility and strength, and can be used in  • Neutralizing – Neutralizers such
                 based etchant that, to cite one  extreme temperatures.                 as sodium bisulfite can help
                 example, was used for the surface                                      ensure the elimination of any
                 treatment on  acrylonitrile-butadiene-  The typical plating on plastic process   excess etchant.
                 styrene (ABS), a thermoplastic terpoly-  involves these steps:       • Pre-activating – Pre-activator
                 mer. The process found usage first in                                  helps in facilitating absorption
                 the automotive industry in the 1970s,  • Cleaning – Requires a mild alka-  during the activation stage of the
                 and a variety of areas such as plumb-  line, or in certain instances, a  plating on plastic process. They
                 ing, electronics and household product  chromic acid solution.         work well with polypropylene or
                 manufacturers adopted it in the 70s  • Pre-dipping – Helps improve the  polyphenylene oxide.
                 and 80s.                            surface of poorly molded, highly  • Activating – Involves the usage of
                    Toronto-based Leader Plating on  stressed parts. Also makes it easier  low-concentration precious metal
                 Plastic is a family-run business that  for etchant to react and attack the  liquid activator, which serves as a
                 has been plating bright chrome on   surface.                           catalyst during plating. Typical
                 plastic since 1979. It began with  • Etching – Etchants generally con-  metals found in activators include
                 appliances for companies like Inglis  sist of sulfuric acid or chromium  platinum, gold and palladium.
                 and Whirpool.                       trioxide solutions, which help to  • Accelerating – Accelerators
                    Now Leader’s clients include a long  increase the substrate surface, thus  removes excess stannous hydroxide
                 list of major automotive manufacturers  enhancing liquid absorption.   from the part, and also prevents
                 where chrome is becoming pervasive.  • Conditioning – An optional step  skip plating occurrence during the
                 “Motorcycles love chrome,” says Rob  in the plating on plastic process,  plating on plastics process.
                 Corazza, Plant Manager.
                    The resins are important. A variety
                 of resins are used for plating on plastic
                 applications, although 90 percent of
                 these applications are ABS, the Grand                                                     NEW
                 View report says. It has an acryloni-
                                                       Coating Thickness Gages
                 trile-styrene matrix which is evenly   Coating Thickness Gages
                 distributed with butadiene rubber,
                 which leads to effective plating. The  2 models
                 butadiene is etched out from the ma-  Ferrous for Steel
                 trix, leaving microscopic holes that are  Combo for All Metals
                 utilized as bonding sites by the plate.
                 Other factors that have encouraged the    Fast, repeatable measurements
                 large scale use of ABS are the ease of  (60+ readings per minute)
                 molding, high metallic adhesion,        Ready to measure—no adjustment
                 affordability and low coefficient of    required for most applications
                 thermal expansion.                      Onscreen averaging for up to 99 readings
                    Other resins that may be used for    Strong, wear-resistant, ruby-tipped probe
                 the plating on plastic process include    Two year warranty on gage body AND probe
                 PEI (polyetherimide), PBT (polybuty-
                 lene terephthalate), LCP (liquid crys-
                 tal polymer), PEEK (polyether ether   www.defelsko.com
                 ketone), and  nylon/polyamide,
                 among others.                           1-800-448-3835
                    PEEK and polypropylene can only                                    simply
                                                                                       simply
                 be plated in a blended form, says
                 Grand View, adding that ABS polycar-                                     measures
                 bonate (ABS/PC) is expected to wit-
                 ness solid demand in the plating on                            DeFelsko Corporation   Ogdensburg, New York USA
                                                                              Tel: +1-315-393-4450   Email: techsale@defelsko.com
                 plastics market in the coming years.
                 www.cfcm.ca                                       Canadian Finishing & Coatings ManuFaCturing 31
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