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Furnace off gas






                            Challenges




                                                                                                                                                                                            Fof
                                                                                                                             Fof
                            ⁄ CO – highly toxic                                                                    Furnace  off  Gas  I  [Bof]                                   Furnace  off  Gas  II  [Bof]
                            ⁄ H – highly explosive –                                             main  components  [Vol.-%]  11  /  13  bar  LSL  Reference  USL  main  components  [Vol.-%]
                                 2
                                                                                                                          CH4
                                                                                                                                                        4
                                                                                                                                                               methane
                                                                                                                                    0
                                                                                                 methane
                               in combination with CO high intention                             ethane                   C2H6      0 0                0.2     ethane
                                                                                                                                                       0,2
                                                                                                                                                               acetylene
                                                                                                 acetylene
                                                                                                                          C2H2
                               to autoignition and backfiring                                    ethylene                 C2H4      0 0                0.2     ethylene
                                                                                                                          C3H8
                                                                                                                                                       0.2
                                                                                                                                                               propane
                                                                                                 propane
                                                                                                 butane                   C4H10     0          Fof     0.2     butane                                         Fof
                            ⁄ fluctuating dust load of the raw gas                               higher  hydro  carbons  C(5+)H(12+)  22      66       0.2     higher  hydro  carbons              Furnace  off  Gas  III  [Bof]
                                                                                                                                    0Furnace  off  Gas  II  [Bof]
                                                                                                 carbon  monoxide
                                                                                                                           CO
                                                                                                                                                               carbon  monoxide
                                                                                                                                                       66
                                                                                                                                              33
                                                                                                                                                       48
                                                                                                                           H2
                                                                                                                                                               hydrogen
                                                                                                 hydrogen          main  components  [Vol.-%] 26  11  /  13  bar  LSL  Reference  USL  main  components  [Vol.-%]
                                                                                                                                             CH4
                                                                                                                                                       0
                                                                                                                                                                          4
                                                                                                                   methane
                                                                                                                                                                                 methane
                                                                                                 nitrogen          ethane  N2       5       C2H6       0 20    nitrogen  0.2     ethane
                                                                                                                                              1
                                                                                                 carbon  dioxide   acetylene  CO2   5       C2H2       0 15    carbon  dioxide  0,2  acetylene
                                                                                                 water  (rel.  humidity)  ethylene  H2O  0  C2H4       80%     water  (rel.  humidity)  ethylene
                                                                                                                                                       0
                                                                                                                                                                         0.2
                                                                                                 oxygen            propane  O2      0       C3H8       0  2    oxygen    0.2     propane
                                                                                                 Type  3,  -  to  be  specified  -   butane  Gasfamily:  STEELGAS  C4H10  0  Fof Type  3,  -  to  be  specified  -   butane
                                                                                                                                                                         0.2
                                                                                                 Type  4,  -  to  be  specified  -   higher  hydro  carbons  C(5+)H(12+) Furnace  off  Gas  III  [Bof]  0.2  higher  hydro  carbons
                                                                                                                                                               Type  4,  -  to  be  specified  -
                                                                                                                                                       0
                                                                                                 Type  6,  -  F58  -  carbon  monoxide       CO       35       Type  6,  -  F57  - 74  carbon  monoxide
                                                                                                                                                                60
                                                                                                                                                                                      USL
                                                                                                                                                                          Reference
                                                                                                                                             H2
                                                                                                                   hydrogen    main  components  [Vol.-%]  13 10/11.2  bar  13  LSL  26  hydrogen
                                                                                                                   nitrogen    methane       N2        5  CH4  23.5  0   25      nitrogen 4
                                                                                                                                                                                      0.2
                                                                                                                   carbon  dioxide  ethane   CO2       5  C2H6  3.5  0   15      carbon  dioxide
                                                                                                                                                                                      0,2
                                                                                                                   water  (rel.  humidity) acetylene  H2O  0  C2H2  0    80%     water  (rel.  humidity)
                                                                                                                   oxygen      ethylene      O2        0  C2H4     0      2      oxygen 0.2
                                                                                                                               propane
                                                                                                                                                                                      0.2
                                                                                                                   Type  3,  -  to  be  specified  -   Gasfamily:  STEELGAS  C3H8  0  Type  3,  -  to  be  specified  -
                                                                                                                                                                                      0.2
                                                                                                                               butane
                                                                                                                   Type  4,  -  to  be  specified  -    C4H10      0             Type  4,  -  to  be  specified  -
                                                                                                                                                                                      0.2
                                                                                                                   Type  6,  -  F57  -  higher  hydro  carbons  C(5+)H(12+)  0   Type  6,  -  F55  -
                                                                                                                               carbon  monoxide           CO       49       59.5      75
                                                                                                                               hydrogen                   H2       7         7        13
                                                                                                                               nitrogen                   N2       5        29        25
                                                                                                                               carbon  dioxide           CO2       5        4.5       15
                                                                                                                               water  (rel.  humidity)   H2O       0                 80%
                                                                                                                               oxygen                     O2       0                  0
                                                                                                                               Type  3,  -  to  be  specified  -   Gasfamily:  STEELGAS
                                                                                                                               Type  4,  -  to  be  specified  -
                                                                                                                               Type  6,  -  F55  -
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