Page 333 - Copper and Bronze in Art: Corrosion, Colorants, Getty Museum Conservation, By David Scott
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Notes
              1  Pedanius Dioscorides De materia medica  5.91  22  Green bice (malachite) was often used from the
                (Dioscorides [1933]  1968).             sixteenth to the eighteenth century in  synthetic
              2  Since there are no  entries in the  I C D D files for   as well as natural form.
                the basic copper (II) formates,  some additional   23  If too much colophony is added, the color of the
                                              G
                X-ray diffraction  data were determined at the C I  mixture becomes less intense.
                Museum Research Laboratory to produce the set   24  Analysis by Narayan Khandekar, C I  Museum
                                                                              G
                of data shown in  A P P E N D I X  D ,  T A B L E  9.  Research Laboratory, Los Angeles, Septem­
              3  Schweinfurt green is the alternate  name for emer­  ber  1997.
                ald  green, a mixed copper acetate-copper arsenite   25  Cennino d'Andrea Cennini The Craftsman's
                salt discussed later in this chapter.   Handbook 56.33 (Cennini [1437]  i960) .
              4  Observations  by the author and Kenneth Hard-  26  Herant Khanjian, letter to the author, 22 Sep­
                castle,  Los  Angeles, June 1999.       tember  1998.
              5  Ashok Roy,  letter to the author,  12 April  1998.  27  Kenneth Hardcastle, conversation with the author,
              6  Peter Mactaggart, letter to the author, with   March 1997.
                samples, 6 July 1997.                 28  Although this formula  is given in the  I C D D  files, it
              7  The use of grapes in the production of verdigris   seems a rather strange empirical formula, and one
                was mentioned by Dioscorides in his De materia   wonders if it should not be ClCu(CH 3COO).
                medica  as early as the first century. He writes   29  John Twilley, conversation with the author,
                that "hiding one mass or plate [of copper] or else   6 April  1999.
                more amongst the huskes of grapes, not pressed   30  Since this formula is very similar to that of pos­
                of late, but growing sour, invert it in like sort"   njakite, Cu 4 S0 4 (OH) 6 -H 2 0, there is a possibility
                (Dioscorides 5.91).                     that posnjakite is actually present. Alternatively,
              8  Harley 2897, Department of Printed Books and   it could be the new compound identified by
                Manuscripts, the British Museum, London.   Strandberg  (see  C H A P T E R  5).
              9  Pliny the Elder Natural History 34.27 (Pliny  1979).  31  The J. Paul Getty Museum's villa site in Malibu
             10  Pliny 34.26.                           was closed to the public in 1998,  and the sculp­
             11  Pliny 34.28.                           tures were removed in 200 0  for  renovation of
             12  Dioscorides 5.91,  s.v. "verdigris."   the villa.
             13  Dioscorides  5.91.                   32  Scheele anticipated Joseph Priestley's discov­
             14  Pliny 34.26.                           ery of oxygen and made many other important
             15  Presbyter  Theophilus De diversis artibus, rec­  discoveries.
                ipe  35  (Theophilus i96i) .          33  This  is the first volume issued by  the  I C D D ,  and
             16  Theophilus, recipe  36.                it is surprising that a material now as obscure
             17  This manuscript is discussed in  C H A P T E R  1 in   as emerald green would have been listed so early
                connection with the plating of iron.    in these files.
             18  Peter Mactaggart, letter to the author, 22 Sep­  34  Arthur Gilbert Dandridge, Hugh Albert Edward
                tember  1996.                           Drescher, John Thomas, and Scottish Dyes Lim­
             19  Alum (potassium aluminium sulfate) was also   ited are named  as inventors in British patent
                known as alume di Roccha, which the Italian met­  322169.
                allurgist Vannoccio Biringuccio (i480-ca.  1539)
                notes is probably derived from "al-Ruha," the
                Arabic name for Edessa (now  Urfa, Turkey)
                (Partington 19 i).  Arie Wallert, however, in a
                         6
                conversation with the author, July 1997,  doubted
                that this was correct and stated that the "roch
                alum" referred to in the recipe probably derives
                from the use of rock or mineral alum, the crude
                initial deposit  as opposed to a purer variety, and
                has nothing to do with Edessa.
             20  A perennial evergreen  shrub with bitter, strongly
                scented leaves, used for thousands of years in
                medicinal preparations.
             21  O. P. Agrawal, conversation with the author,
                Lucknow, India, April  1996.





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