Page 110 - Chemistry
P. 110

-
                                        +
                                      2T (aq) + 2e                 T 2(g)         0.00
                                                -
                                      U 2+ (aq) + 2e               U(s)           -0.13
                                                -
                                      V 2+ (aq) + 2e               V(s)           -0.76
                                   
                     (i) What is the E  value of the weakest reducing agent?
                     (ii) Which element is likely to be hydrogen? Give a reason for your answer
                     (iii) Draw a diagram for the cell that would be obtained when the half cell of elements
                             S and V  are combined
                     (iv) Calculate the e.m.f of the electrochemical cell in a (iii) above





                 (b) The diagram below represents the electrolysis of dilute sulphuric (VI) acid









                 (i) Name the gases X and Y
                     (ii) Write ionic equation for the formation of gas X
                   (iii) At what electrode does reduction take place? Explain your answer
                   (iv) Name the most suitable electrodes for this experiment. Explain your answer

          25.    The flow chart below shows an analysis of mixture R that contains two salts. Study it
                      and answer the questions that follow:-


                                        Mixture R
                           Add water then filter
                                Step IV        Divide into two portions         Two metal oxides + CO 2 +
                                                       Step I                   NO 2 + O 2 +H 2O
                                                                               Step II
                                                                            Add dil. H 2SO 4

                 Residue V                Filtrate W                                               Residue
                         Step V                                               Filtrate X
                         Add HNO 3
                                                                             Step III
                Solution Z + CO 2                               Add excess                         Add excess
                                                                  NH 4OH                             NaOH
                                                                    Colourless                 Colourless
                   Add excess NaOH        Add excess NH 4OH to        solution                   solution
                    to portion of Z            portion of Z

                Colourless              White
                 solution             precipitate


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