Page 160 - Chemistry

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Volume of solution T added (cm )
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Volume of solutions S + T (cm )
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Temperature of mixture ( C)
(c) From the graph, determine:-
(i) The volume of solution T required to react completely with solution S
(ii) The highest temperature change, T
(d) Calculate the heat change for the reaction ;
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(Heat change = M x 4.2Jg C x t, assume the density of the solution to be 1g/cm )
(e) Calculate the number of moles of the sodium hydroxide solution T used in the experiment
(f) Calculate the number of moles of the hydrochloric acid, solution S used in the experiment
(g) Determine the heat of reaction per mole of hydrochloric acid, solution S
3. You are provided with solid U, carry out the test below. Record your observations and
inferences in the table. Identify any gas(es) evolved .

(a) Heat a spatula end full of mixture U in a test tube.
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(b) (Dissolve a part of mixture U in abort 10cm of distilled water
(c) Filter the mixture and retain both filtrate and the residue. Divide the filtrate into two portions.
(i) To the first portion, add sodium hydroxide drop wise until in excess
ii) To the second portion, add Potassium iodide solution

(d) Divide the residue into two parts:-
(i) Put one part in a test tube and add dilute nitric acid until the residue just dissolves
(ii) Divide the resulting solution into two parts. To part one, add dilute sodium hydroxide solution
drop wise until in excess
(iii) To part two, add aqueous ammonia drop wise until in excess

RACHUONYO DISTRICT

CONFIDENTIAL
INSTRUCTIONS .
In addition to common fittings, apparatus and chemicals found in the school laboratory.
Each candidate requires:-
1. 50.0ml burette
2. 250ml pipette
3. Pipette filler
4. Two 25.0ml conical flasks
5. A clean metallic spatula
6. One boiling tube
7. A white tile/plain paper (white)
8. Eight clean dry test-tubes on a rack
9. 1.5g of carbonate A- accurately weighed and placed in a stoppered test-tube
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10. 75cm of 0.1M sodium hydroxide labeled C
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11. 75cm of 1M hydrochloric acid labeled solution B
12. 10ml measuring cylinder
13. One filter paper
14. A filter funnel
15. A glass rod
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16. 45cm of 0.42M glucose, labeled X
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17. 130cm of 2.0M H 2SO 4 labelled Z
18. 10ml of 0.04M KMnO 4 labelled Y
19. Stop watch/stop clock
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20. Thermometer (-10 C – 110 C)
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