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Answers to Advanced Chemistry Exercises


                   1.  Determine the number of moles of N 2O 4 needed to react completely
                       with 2.56 mol of N 2H 4 for the reaction 2 N 2H 4(l) + N 2O 4(l) → 3 N 2(g) +
                       4 H 2O(l)

                       Find the relation between moles of N 2H 4 and N 2O 4 by using the
                       coefficients of the balanced equation: 2 mol N 2H 4 is proportional to 1
                       mol N 2O 4 Therefore, the conversion factor is 1 mol N 2O 4/2 mol N 2H 4:

                       moles N 2O 4 = 2.56 mol N 2H 4 x 1 mol N 2O 4/2 mol N 2H 4

                       moles N 2O 4 = 1.28 mol N 2O 4 (answer)


                   2.  Determine the number of moles of N 2 produced for the reaction 2
                       N 2H 4(l) + N 2O 4(l) → 3 N 2(g) + 4 H 2O(l) when the reaction begins with
                       4.52 moles of N 2H 4.


                       Find the relation between moles of N 2H 4 and N 2 by using the
                       coefficients of the balanced equation: 2 mol N 2H 4 is proportional to 3
                       mol N 2 In this case, we want to go from moles of N 2H 4 to moles of N 2,
                       so the conversion factor is 3 mol N 2/2 mol N 2H 4:

                       moles N 2 = 4.52 mol N 2H 4 x 3 mol N 2/2 mol N 2H 4


                       moles N 2 = 6.78 mol N 2O 4 (answer)

                   3.   The balanced equation for the synthesis of ammonia is 3 H 2(g) +
                       N 2(g) → 2 NH 3(g).  From the balanced equation, it is known that:
                       1 mol N 2 ∝ 2 mol NH 3

                       Use the periodic table to look of the atomic weights of the elements to
                       calculate the weights of the reactants and products:

                       1 mol of N 2 = 2(14.0 g) = 28.0 g
                       1 mol of NH 3 is 14.0 g + 3(1.0 g) = 17.0 g

                       These relations can be combined to give the conversion factors needed
                       to calculate the mass in grams of NH 3 formed from 72.0 g of N 2:

                       mass NH 3 = 72.0 g N 2 x 1 mol N 2/28.0 g NH 2 x 2 mol NH 3/1mol NH 3 x
                       17.0 g NH 3/1 mol NH 3

                       mass NH 3 = 87.43 g NH 3 (answer)




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