Page 73 - Statistics presented by Dr. Sara Ismail Aborass
P. 73

9/8/2023

Colloidal ppts tend to peptize if washed
with pure water because water will
dilute and remove electrolytes.

Peptization is the reverse of
coagulation

Electrolyte

Colloidal solution  Coagulated ppt

Peptization

                 To prevent peptization, add electrolyte to the
                  washing liquid (eg: volatile HNO3 or NH4OH)

143

              5) Drying and ignition

            • Drying: heating the ppt at temperature
              <250°C not accompanied with change
              in chemical structure of ppt
               Ex: AgCl

            • Ignition: heating the ppt at temperature
              > 250°C usually accompanied with
              change in chemical structure of ppt
               Ex: CaC2O4.H2O

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