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90   The Chemistry and Fertility of Soils under Tropical Weeds



                                     -
                                                      +
                                                            2-
                              R—OSO 3   +  H 2 O  R—OH  +  H   +  SO 4    .......   Eq. 6.1

                           Eq. 6.1 clearly shows that the decomposition of organic S also needs the presence
                           of water molecules.  Therefore, moistening the organic S is important to release S
                           from  the  organic  materials.  Unlike  the  decomposition  of  organic  P,  the
                           decomposition  of  organic  S  will  acidify  the  soil  system  because  this  reaction
                                    +
                           produces H  ions.  The soil containing organic S may become more acidic with time
                           of decomposition.
                              Like C, N is originated from atmosphere (Fig. 1.9).  The atmosphere actually
                           contains  approximately  78%  N 2   which  is  not  available  to  vegetation.    Unlike  C,
                           which is directly absorbed by plants as CO 2  through leaf or stem stomata, N can be
                           absorbed  by  plant  roots  in  a  particular  form  after  encountering  relatively  long
                           processes.    Atmospheric  N  initially  enters  the  bodies  of  bacteria  and  particular
                           vegetation roots in the soil – plant system through a process called N Fixation.  The
                           bacteria  involved  in  the  fixation  are  called  Nitrogen  Fixing  Bacteria  (Rendig  and
                           Taylor, 1989).  Among these bacteria there is Rhizobium sp. that live symbiotically
                           with the roots of legumes.
                                                                             +
                                                                                     -
                              In the soil environment N is finally transformed to be NH 4  and NO 3 , which are
                           available for vegetation root absorption and are utilized by plants to form various
                           structural  and  functional  substances.    These  structural  and  functional  N  in  plant
                           tissues  and  in  microorganisms  are  finally  changed  into  inorganic  N  that  can  be
                           absorbed by plant roots after encountering decomposition processes.  A part of the
                           inorganic  N  also  volatilizes  into  the  atmosphere,  particularly  in  a  reductive  soil
                           environment.  All the processes of N transformation from N 2  in the atmosphere to
                                       -
                              +
                           NH 4   and  NO 3 in  soil  water,  and  then  their  absorption  by  plant  roots  and
                           transformation  to  be  structural  and  functional  substances  in  plant  tissues  and
                           microorganisms, and then their ultimate decomposition back to form inorganic N
                              +        -
                           (NH 4  and NO 3 ) that are available to vegetation roots build a cycle.  This cycle is
                           called Nitrogen Cycle or N-Cycle as shown previously in Fig. 1.9.
                              The organisms that can fix the atmospheric N is the Nitrogen Fixing Bacteria;
                           so-called  due  to  their  ability  to  fix  and  incoorporate  atmospheric  N  into  their
                           bodies.    A  part  of  these  bacteria  such  as  Rhizobium  sp.  lives  symbiotically  with
                           particular  vegetation  roots.    Legumes  and  peanuts  are  two  of  these  particular
                           plants.    In  this  symbiosis,  vegetation  supplies  nutrients  and  water  needed  by
                           bacteria, while bacteria supply N for plants.  In addition to these bacteria that live
                           symbiotically, there are also free nitrogen fixing bacteria in soils living outside of
                           plant root nodules.  Among these bacteria are Azotobacter and Azospillum.  These



                           Abdul Kadir Salam and Nanik Sriyani – 2019
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