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70                             drilling), or was it biogenic meth-   In light of these findings, Osborn’s
                                                           ane produced at shallow depths    team recommended more research into
                                             Active
                                             extraction    by microorganisms (p. 543)? To    methane’s underground movements,
                            60               areas         determine this, they analyzed ratios   as well as “long-term coordinated sam-
                                             Nonactive     of isotopes (p. 42) of carbon and   pling and monitoring” near drilling sites.
                                             extraction    hydrogen in the methane as well as   They also urged that more data should
                          Methane concentration (mg CH 4  /L)  40  Action level for  methane from well water near drill-  PNAS, critiquing the paper. Some
                                             areas
                            50
                                                                                             be required—and made public—before
                                                           ratios of methane to other hydrocar-
                                                                                             drilling proceeds.
                                                           bon gases.
                                                                                                 Several researchers wrote to
                                                              Their analyses showed that the
                                                                                             thought the results did not rule out
                                                           ing sites was thermogenic gas that
                                                                                             natural seepage or the effects of
                                                           had originated deep underground. In
                            30
                                                                                             past drilling. Some felt the fact that
                                                           contrast, methane present in small
                                                                                             they did not find fracking fluids in the
                                                           amounts in wells far from drilling sites
                                         hazard mitigation
                                                           was mostly of shallow biogenic origin.
                            20
                                         (US Department
                                                                                             not have come from hydrofracking.
                                                           Moreover, the chemistry of the natu-
                                         of Interior)
                                                                                             Others complained that the sampling
                                                           ral gas in wells near drilling sites was   aquifers meant the methane could
                            10                             consistent with the chemistry of the   of homeowners was nonrandom. All
                                                           Marcellus Shale formation underly-  pointed out that to truly determine
                                                           ing the region. This suggested that   whether fracking was responsible for
                             0                             the methane near drilling sites likely   methane in groundwater, one would
                                1000  2000  3000  4000  5000  6000  resulted from drilling.  need to make careful comparisons
                              0
                               Distance to nearest gas well (m)  Still, the Marcellus Shale lies   of wells before and after drilling
                                                           1–2 km below the surface, whereas   occurred.
                        Figure 2 Methane concentrations were   the drinking water wells extend   While countering most of these
                        far higher at water wells near gas drilling   only 36–190 m underground. How   complaints, Osborn’s team agreed that
                        sites (left end of graph) than at wells far   could methane from so far down   the sampling of homeowners was non-
                        from them (right end of graph). Data from   have reached these shallow wells?   random, but said this is unavoidable
                        Osborn, S.G. et al., 2011. Methane contamination                     when researchers need to seek their
                        of drinking water accompanying gas-well drilling   Osborn’s team proposed three pos-  permission for sampling.
                        and hydraulic fracturing. PNAS 108: 8172–8176.  sible ways:
                                                                                                 Osborn’s team agreed with its
                               Let’s say you are going to   1.  Gas-rich solutions from deep under-  critics that before-and-after com-
                               sample two new water wells for   ground were displaced by fracking   parisons of water quality in areas
                        methane, one just 250 m from a gas   and traveled upward through existing   where drilling occurred would offer
                        drilling site, and one 5000 m from a   fractures to the shallow aquifer. (This   the best way to determine whether
                        drilling site. Based on the data shown                                                                    CHAPTER 7 • Envi R onm E n TA l Poli C y :  mA king D EC i si ons  A n D   s olving P R obl E m s
                        here, predict, for each of these wells, the   explanation seemed unlikely to the   hydrofracking has impacts on water
                        likelihood that methane concentrations   researchers, given that fracking fluids   quality. They pointed out that such
                        will be above the “Action level for hazard   and salty fluids from deep under-  a comparison could easily be done,
                        mitigation.”                         ground had not gotten into the wells.)  because the gas industry possesses
                                                           2.  Fracking unintentionally created or   archived data from many hundreds
                                                             enlarged fractures in shallow areas   of water wells in Pennsylvania before
                        the range of the federal government’s   far above the shale formations,   drilling began. Osborn’s team pro-
                        defined action level for hazard mitiga-  allowing gas to travel to the surface.   posed that they would gladly col-
                        tion. Nine samples were above the    (The researchers judged this expla-  laborate with industry, landowners,
                        action level.                        nation unlikely but possible.)  independent analysis labs, and
                            The team then sought to deter-  3.  Some gas well casings were leaking,   the Pennsylvania Department of
                        mine where this methane had come     allowing gas pulled up from deep   Environmental Protection to conduct
                        from: Was it thermogenic methane     below to escape from the well casing   a joint study using such data. To date,
                        produced deep underground along      near the surface and infiltrate shallow   the researchers have yet to receive an
                        with fossil fuel formation (which    aquifers. (The team judged this to be   agreement from the gas industry to
                        would suggest contamination from     the most likely explanation.)   conduct such studies.



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           M07_WITH7428_05_SE_C07.indd   185                                                                                    12/12/14   2:57 PM
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