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ide (CO ). As we pump excess CO  into the atmosphere
                                                               Chloride,            2                       2
                                                                 –
                                                               Cl (1.9%)     by burning fossil fuels, more CO  diffuses into the oceans.
                                                                                                         2
                                                                             We shall soon see (pp. 446–447) how this affects ocean pH
                                                               Sodium,       (p. 46), turning the water more acidic and posing problems
                                                                 +
                                                               Na   (1.1%)   for marine life.
                                                               Sulfate,
                                                               SO 4 2–  (0.3%)  Solar energy structures ocean water
                                                               Magnesium,
                                                               Mg 2+   (0.1%)  from surface to bottom
                                                               Calcium,      Sunlight warms the ocean’s surface but does not penetrate
                             Ocean water                       Ca 2+   (0.04%)  deeply, so ocean water is warmest at the surface and becomes
                                                               Potassium,
                                                                +
                                                               K (0.04%)     colder with depth. Surface waters in tropical regions receive
                                                               Bicarbonate,   more solar radiation and therefore are warmer than surface
                                                               HCO 3 –   (0.01%)  waters  in temperate  or polar regions. Warmer water  is less
                                                                             dense than cooler water, but water also becomes denser as it
                                                                             gets saltier. This occurs because as salt dissolves in water, it
                                                                             increases solution mass (the mass of water and its dissolved
                                              3.5%                           salts) more than it increases solution volume. These relation-
                        Figure 16.4 Ocean water consists of 3.5% salt, by mass.   ships give rise to different layers of water: Heavier (colder and
                        Most of this salt is NaCl in solution, so sodium and chloride ions   saltier) water sinks, whereas lighter (warmer and less salty)
                        are abundant. A number of other ions and trace elements are also   water remains nearer the surface. Waters of the surface zone
                        present.                                             are heated by sunlight and stirred by wind such that they are

                               If you had a beaker containing one kilogram (1000 grams)   of similar density down to a depth of about 150 m (490 ft).
                               of seawater, how many grams of salt are in the beaker? Of   Below this zone lies the pycnocline, a region in which density
                        this salt, how many grams are from negatively-charged ions?  increases rapidly with depth. The pycnocline contains about
                                                                             18% of ocean water by volume, compared to the surface
                                                                             zone’s 2%. The remaining 80% lies in the deep zone beneath
                        (Figure 16.4). Ocean water is salty primarily because ocean   the pycnocline. The dense water in this deep zone is sluggish
                        basins are the final repositories for water that runs off the land.   and unaffected by winds, storms, sunlight, and temperature
                        Runoff on land collects salts from minerals in weathered rocks   fluctuations.
                        and carries them, along with sediments, to the ocean. Wind   Despite the daily heating and cooling of surface waters,
                        also blows salts from the land out to sea. Whereas the water in   ocean temperatures are much more stable than temperatures on
                        the ocean evaporates, the salts do not, and they accumulate in   land. Midlatitude oceans experience yearly temperature varia-
                        ocean basins. If we were able to evaporate all the water from   tion of only around 10°C (18°F), and tropical and polar oceans
                        the oceans, their basins would be left covered with a layer of   are still more stable. The reason for this stability is that water
                        dried salt 63 m (207 ft) thick.                      has a high heat capacity, a measure of the heat required to
                            The salinity of ocean water generally ranges from 33,000   increase temperature by a given amount. It takes more energy
                        to 37,000 parts per million, varying from place to place   to increase the temperature of water than it does to increase the
                        because of differences in evaporation, precipitation, and   temperature of air. High heat capacity enables ocean water to
                        freshwater runoff (freshwater has less than 500 parts per mil-  absorb a tremendous amount of heat from the air. In fact, just
                        lion salinity) from land and glaciers. Coastal waters are often   the top 2.6 m (8.5 ft) of the oceans holds as much heat as the
                        less saline because of the influx of freshwater runoff. Salinity   entire atmosphere! By absorbing heat and releasing it to the
                        near the equator is low because this region has a great deal of   atmosphere, the oceans help regulate Earth’s climate (Chapter
                        precipitation, which is relatively salt free. In contrast, surface   18). They also influence climate by moving heat from place to   CHAPTER 16 • M AR in E   A nd Co A s TA l  s ys TEM s  A nd R E sou R CE s
                        salinity is high at latitudes roughly 30–35 degrees north and   place via the ocean’s surface circulation, a system of currents
                        south, where evaporation exceeds precipitation.      that move in the pycnocline and the surface zone.
                            Besides dissolved salts, nutrients such as nitrogen and
                        phosphorus occur in seawater in trace amounts (well under 1   Surface water flows horizontally in currents
                        part per million) and play essential roles in nutrient cycling
                        (p. 135) in marine ecosystems.  Another aspect of ocean   Earth’s ocean is composed of vast, riverlike flows driven by
                        chemistry is dissolved gas content. Roughly 36% of the gas   density differences, heating and cooling, gravity, and wind.
                        dissolved in seawater is oxygen, which is produced by pho-  Surface  currents flow horizontally within the upper 400 m
                        tosynthetic plants, bacteria, and phytoplankton (p. 93) and   (1300 ft) of water for great distances and in long-lasting
                        enters by diffusion from the atmosphere. Oxygen concentra-  patterns across the globe (Figure 16.5). Warm-water  cur-
                        tions are highest in the upper layer of the ocean, reaching 13   rents carry water heated by the sun from equatorial regions,
                        ml/L of water. Marine animals depend on dissolved oxygen,   while cold-water currents carry water cooled in high-latitude
                        and if oxygen is depleted, a hypoxic “dead zone” may ensue,   regions or from deep below. Some surface currents are very
                        killing animals or forcing them to leave (pp. 123, 428–429).   slow. Others, like the Gulf Stream, are rapid and powerful.
                        Another gas that is soluble in ocean water is carbon diox-  From the Gulf of Mexico, the Gulf Stream flows up the U.S.   441







           M16_WITH7428_05_SE_C16.indd   441                                                                                    12/12/14   3:06 PM
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