Page 478 - Environment: The Science Behind the Stories
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oxygen (O ) to form SO . Once in the atmosphere, SO  may   200
                                                                     2
                                 2
                                            2
                        react to form sulfur trioxide (SO ) and sulfuric acid (H SO ),                                   300
                                                                     2
                                                                        4
                                                   3
                        which may then settle back to Earth in acid deposition (p. 491).  150          Year       (–99%)  250
                                                                                                          1970
                                                                                                          2012
                        Nitrogen oxides  Nitrogen oxides are a family of compounds      (–73%)         (% change)        200
                        that include nitric oxide (NO) and nitrogen dioxide (NO ). Nitro-  100
                                                                   2
                        gen oxides result when atmospheric nitrogen and oxygen react at   Millions of tons emitted       150  Thousands of tons
                        high temperatures. Most U.S. NO  emissions result from com-                                      100
                                                   X
                        bustion in vehicle engines. Electrical utility and industrial com-  50  (–62%)
                        bustion account for most of the rest. NO  emissions contribute to   (–58%)    (–83%)             50
                                                       X
                        smog, acid deposition, and stratospheric ozone depletion.                          (–85%)
                                                                                  0                                      0
                                                                                                 VOCs
                        Volatile organic compounds  Volatile organic compounds        CO    NO x Air pollutant SO 2  PM 10  Pb
                        (VOCs) are carbon-containing chemicals used in and emitted by
                        vehicle engines and a wide variety of solvents, industrial pro-  (a) Declines in six major pollutants
                        cesses, household chemicals, and consumer items. One group of
                        VOCs consists of hydrocarbons (p. 46) such as methane (CH ,   250                             +212%
                                                                         4
                        the primary component of natural gas), propane (C H , used   200
                                                                  3
                                                                    8
                        as a portable fuel), butane (C H , found in cigarette lighters),                      +167%
                                                4
                                                  10
                        and octane (C H , a component of gasoline). Human activities   150
                                     18
                                   8
                        account for about half the VOC emissions in the United States.   100
                        The remainder comes from natural sources; for example, plants   Percent change (1970–2011)  +52%  +45%
                        produce isoprene and terpenes, compounds that generate a blu-  50
                        ish haze that has given the Blue Ridge Mountains their name.   0
                        VOCs can react to produce a number of secondary pollutants.  –50
                        Particulate matter  Particulate matter is composed      –100  –68%
                                                                                                              Vehicle
                                                                                                      Energy
                        of solid or liquid particles small enough to be suspended in   Emissions Population consumption miles  GDP
                        the atmosphere and able to damage respiratory tissues when                            traveled
                        inhaled. Particulate matter includes primary pollutants such as   (b) Trends in major indicators
                        dust and soot, as well as secondary pollutants such as sulfates
                        and nitrates. Scientists classify particulate matter by the size of   Figure 17.14 U.S. emissions have declined sharply since
                        the particles. PM  pollutants consist of particles less than 10   1970. We have achieved reductions (a) in the six major pollut-
                                      10
                        microns in diameter (one-seventh the width of a human hair),   ants tracked by the EPA, despite increases (b) in U.S. population,
                        whereas PM  pollutants consist of still-finer particles less   energy consumption, vehicle miles traveled, and gross domestic
                                   2.5
                        than 2.5 microns in diameter. Most PM  pollution is from road   product. Data from U.S. EPA.
                                                       10
                        dust, whereas most PM  pollution results from combustion.
                                           2.5                                     By what percentage has population increased since 1970?
                                                                                   By what percentage have emissions decreased? Using
                        Lead  Lead is a heavy metal that enters the atmosphere as a   these two amounts, calculate the change in emissions per person.
                        particulate pollutant. The lead-containing compounds tetraethyl
                        lead and tetramethyl lead, when added to gasoline, improve   in emissions have occurred despite significant increases in the   CHAPTER 17 • AT m os PHER i C   sC i E n CE , Ai R  Qu A li T y,  A nd Poll u T i on Con TR ol
                        engine performance. However, exhaust from the combustion of   nation’s population, energy consumption, miles traveled by
                        leaded gasoline emits airborne lead, which can be inhaled or can   vehicle, and gross domestic product (Figure 17.14b). Likewise,
                        be deposited on land and water. Lead can enter the food chain,   most other industrialized nations have taken their own steps to
                        accumulate in body tissues, and cause central nervous system   reduce emissions and have attained similar results.
                        malfunction and many other ailments (p. 385). Since the 1980s,   We have achieved this success in controlling pollution
                        leaded gasoline has been phased out in most industrialized   as a result of policy steps and technological developments,
                        nations (p. 26), and as a result lead pollution has plummeted.   each motivated by grassroots social demand for cleaner
                        The United States led the way, Mexico City phased out leaded   air. Cleaner-burning motor vehicle engines and automo-
                        gasoline in the 1990s, and today most developing nations are   tive technologies such as catalytic converters (Figure 17.15)
                        following suit, although auto exhaust still creates significant lead   have played a large part, reducing the emissions of carbon
                        pollution in many of them. In developed nations today, the main   monoxide and other pollutants from motor vehicles. In fac-
                        source of atmospheric lead pollution is industrial metal smelting.  tories, power plants, and refineries, technologies such as
                                                                             baghouse filters, electrostatic precipitators, and scrubbers
                        We have reduced pollutant emissions                  (Figure 17.16) have been installed to chemically convert or
                                                                             physically remove airborne pollutants before they are emit-
                        Since passage of the Clean Air Act of 1970, the United States   ted from smokestacks. The sulfur-dioxide permit-trading
                        has reduced emissions of each of the six monitored pollut-  program (p. 201) and clean coal technologies (p. 555) have
                        ants substantially (Figure 17.14a). These dramatic reductions   reduced SO  emissions. And phaseouts of leaded gasoline   477
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