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WPS-ITW-082 -  LPS® SAFE-MARK FOOD CONTACT                                    Revision Date  28-Sep-2017
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                                                                                    4-Methyl-pentan-2-on
                 Cyclohexanone                                                                        0.049 µmol/mmol
                    108-94-1                                                                        Creatinine urine end of
                                                                                                       shift at end of
                                                                                                        workweek
                                                                                                     1,2-Cyclohexanediol
                                                                                                      after hydrolysis
                                                                                                     50 mg/g Creatinine
                                                                                                     urine end of shift at
                                                                                                      end of workweek
                                                                                                     1,2-Cyclohexanediol
                                                                                                      after hydrolysis
                 Chemical Name        Denmark           Finland         France          Germany         Gibraltar
               Methyl isobutyl ketone                               2 mg/L urine end of  0.7 mg/L urine end of
                    108-10-1                                             shift            shift
                                                                   Methylisobutylketone 4-Methylpentan-2-one
                 Chemical Name         Hungary          Ireland          Italy           Latvia        Luxembourg
               Methyl isobutyl ketone               1 mg/L urine end of  (ACGIH:) 1 mg/L urine
                    108-10-1                       shift Methyl isobutyl  end of shift MIBK
                                                        ketone
                 Cyclohexanone                      8 mg/L urine end of  (ACGIH:) 80 mg/L
                    108-94-1                        shift Cyclohexanol  urine end of shift at
                                                      nonspecific,   end of workweek
                                                       metabolite   1,2-Cyclohexanediol
                                                   80 mg/L urine end of  (with hydrolysis)
                                                         shift        Nonspecific,
                                                   1,2-Cyclohexanediol  semi-quantitative
                                                      nonspecific  (ACGIH:) 8 mg/L urine
                                                                       end of shift
                                                                    Cyclohexanol (with
                                                                       hydrolysis)
                                                                      Nonspecific,
                                                                     semi-quantitative
                   Chemical Name            Slovakia             Spain            Switzerland       United Kingdom
                 Methyl isobutyl ketone  3.5 mg/L urine end of  1 mg/L urine end of shift  2 mg/L urine end of shift
                      108-10-1          exposure or work shift  Methyl isobutyl ketone  2  4-Methylpentan-2-one
                                        4-Methyl-2-pentanone
                                             Hexone
                   Cyclohexanone                            80 mg/L urine end of  100 mg/L urine end of
                      108-94-1                                  workweek       shift, and after several
                                                          1,2-Cyclohexanodiol (with  shifts (for long-term
                                                             hydrolysis)  1;9;I;S  exposures) total
                                                           8 mg/L urine end of shift  1,2-Cyclohexandiol
                                                            Cyclohexanol (with  12 mg/L urine end of shift,
                                                             hydrolysis)  2;9;I;S  and after several shifts (for
                                                                               long-term exposures)
                                                                                total-Cyclohexanol
            Derived No Effect Level        No information available.

            Predicted No Effect Concentration  No information available.
            (PNEC)


            8.2.  Exposure controls

            Engineering Measures           Showers
                                           Eyewash stations
                                           Ventilation systems
            Personal protective equipment  Personal protection equipment should be chosen according to the CEN standards
               Eye Protection              Tightly fitting safety goggles.
               Skin and Body Protection    Long sleeved clothing.
               Hand Protection             Protective gloves.
               Respiratory Protection      When workers are facing concentrations above the exposure limit they must use
                                           appropriate certified respirators.


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