Page 28 - 201902 SCA February 2019 Volume 56 Number 1
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Technical ARTICLE                            Studies of pre-treatment in various woods with high
                                                                  performance light stabilizers


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                     Screening Design of Different Type of Woods and   (X2-1: Top Coat: Waterborne Acrylic Resin, X2-2:
                     Co-solvents by using EV-AQ and EV-SB            Wood Pretreatment: Butyl Carbitol mixed with EV-
                     Screening design (Table 7) was used to identify   SB, Top Coat: EV-AQ mixed with Acrylic Resin and
                     factors that get the minimal color change after   X2-3: Wood Pretreatment: IPA mixed with EV-SB, Top
                     weathering test. Mathematical model derived from   Coat: EV-AQ mixed with Acrylic Resin). The Analysis
                     data indicates all factors –X1: 5 different type of   of variance, parameter estimates and effect tests are
                     woods (Cedar, Douglas fir, Southern beech, African   shown in Table 8, Table 9 and Table 10.
                     Teak and Southern pine). X2: 3 type of treatments
                                                                     The Optimal Prediction Profiler
                                                                     The prediction profiler (for example, Southern
                                                                     pine) shows the effect of 3 types of treatment after
                                                                     weathering test for 300 hrs. For the item which
                                                                     uses waterborne acrylic resin only, the yellowing
                                                                     after weathering test is significant. (color difference
                                                                     ΔE=31.85) (as shown in Figure 4, page 28). 10% EV-
                                                                     SB is mixed with Butyl Carbitol in the pretreatment
                                                                     and 2% EV-AQ in top coat. The performance is
                                                                     better than the Blank (color difference ΔE=10.25) (as
                                                                     shown in Figure 5, page 28). The 10% EV-SB mixed
                                                                     with IPA in the pretreatment and 2% EV-AQ in top
                                                                     coat. The light fastness of Southern Pine is the best.
                                                                     (color difference ΔE=6.55) (as shown in Figure 6,
                                                                     page 29). The photos of different type woods after
                                                                     weathering test are shown in Figures 7 to 11 (see
                                                                     page 30).

                                                                     RESULTS
                                                                     After weathering test, the result shows that the
                                                                     mixture of Eversorb® SB and Eversorb® AQ can
                                                                     significantly protect wood surfaces from yellowing. In
                                                                     addition, Eversorb® SB mixed with isopropyl alcohol
                                                                     can provide better performance than Eversorb® SB
                                                                     mixed with butyl carbitol.
                                                                     CONCLUSION
                                                                     Environmentally friendly coatings are the trend for
                                                                     future development. We have developed several
                                                                     unique products specifically for coatings.
                                                                     Eversorb® AQ, a blend of UV absorber and HALS,
                                                                     is developed for waterborne clear coats. Eversorb®
                                                                     SB, designed for wood pretreatments, can protect
                                                                     lignin from UV light degradation.

                                                                     Lignin is a complex organic polymer containing
                                                                     hydroxyl functional groups (-OH). The solubility
                                                                     parameters of isopropyl alcohol and butyl carbitol
                                                                     are 11.5 and 9.9, respectively. After weathering test,
                                                                     the result shows Eversorb® SB can provide better


     26 Journal of Surface Coatings Australia • February 2019
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