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plating and anodizing: CHROME REGULATIONS


         New Chromium Electroplating,


         Chromium Anodizing and Reverse


         Etching Regulations Take Effect




         BY STEWART TYMCHUK

         SOR/2009-162
         Recently, the Chromium Electroplating, Chromium Anodiz-
         ing and Reverse Etching Regulation was amended. The
         goals of the regulatory amendments were to both provide
         more flexibility and consistency for facilities to comply
         with the Regulations and to clarify regulatory requirements
         in light of currently available technologies.
           In essence, the Regulations previously required surface
         tension measurements be made with a tensiometer and
         be performed in accordance with ASTM D 1331-89
         (re-approved 2001), Standard Test Methods for Surface
         and Interfacial Tension of Solutions of Surface-Active
         Agents. New and different types of tensiometers are now
         available which are not based on the principles of the du
         Nouy tensiometer and therefore do not require a reference
         to ASTM D 1331-89.

         APPLICATIOn
                                                            The Kibiron AquaPi+ is one example of
         These regulations apply to any facility that uses a solution   a high precision tensiometer which can now be used
         containing a hexavalent chromium compound for      under the new regulations for more reliable, faster, and precise measurements.
         chromium electroplating, chromium anodizing or reverse
         etching in a tank where 50 kg or more of chromium trioxide
         (CrO3) is used per calendar year.                  (4)  Each facility intending to change either the method
                                                                of controlling the release of hexavalent chromium
         GEnERAL REquIREMEnTS                                   compounds from a tank or the surface tension meas-
         (1)  Each facility, where the regulation applies, must con-  urement method for a tank must notify the Ministry.
            trol the release of hexavalent chromium compounds
            from each tank by one of the following methods:   uSE OF A POInT SOuRCE
            • using a point source;                         Each facility that controls the release of hexavalent
            • limiting the surface tension of the solution    chromium compounds from a tank by using a point source
              in the tank;                                  must use a control device in the emission collection system
            • using a tank cover.                           and must not release more than 0.03 mg/dscm of hexavalent
                                                            chromium from any point source.
         (2)  Each facility must submit a notice to the Minister    Each facility required to comply must perform a release
            indicating, for each tank, the method used to control   test establishing compliance at each point source and per-
            the release of hexavalent chromium compounds.   form a new release test at least every five years afterwards,
                                                            providing the average of three sampling runs from that test
         (3)  If the release of hexavalent chromium compounds   did not exceed 0.03 mg/dscm of hexavalent chromium
            from a tank is controlled by limiting the surface    from any point source.
            tension of the solution, the notice must state whether   These tests must be repeated if the facility has replaced
            a tensiometer or a stalagmometer is or will be used   a control device, increased the total surface area of the
            to measure surface tension.                     solution by more than 25 percent or made changes to
                                                            the ventilation system that affected the velocity or the
                                                            flow rate.

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