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low level of acceptance in those days.  The blend contains 40 to 60 percent   this helps in promoting a more uni-
         However, the adhesive properties of  of ABS, while the remaining is made   form absorption during the activa-
         plastics were enhanced through the  up of PC. This mixture offers high duc-  tion stage.
         implementation of a chromic acid-  tility and strength, and can be used in  • Neutralizing – Neutralizers such
         based etchant that, to cite one   extreme temperatures.               as sodium bisulfite can help
         example, was used for the surface                                     ensure the elimination of any
         treatment on  acrylonitrile-butadiene-  The typical plating on plastic process    excess etchant.
         styrene (ABS), a thermoplastic terpoly-  involves these steps:       • Pre-activating – Pre-activator
         mer. The process found usage first in                                 helps in facilitating absorption
         the automotive industry in the 1970s,  • Cleaning – Requires a mild alka-  during the activation stage of the
         and a variety of areas such as plumb-  line, or in certain instances, a   plating on plastic process. They
         ing, electronics and household product   chromic acid solution.       work well with polypropylene or
         manufacturers adopted it in the 70s  • Pre-dipping – Helps improve the   polyphenylene oxide.
         and 80s.                            surface of poorly molded, highly   • Activating – Involves the usage of
           Toronto-based Leader Plating on   stressed parts. Also makes it easier   low-concentration precious metal
         Plastic is a family-run business that   for etchant to react and attack the   liquid activator, which serves as a
         has been plating bright chrome on   surface.                          catalyst during plating. Typical
         plastic since 1979. It began with    • Etching – Etchants generally con-  metals found in activators include
         appliances for companies like Inglis   sist of sulfuric acid or chromium   platinum, gold and palladium.
         and Whirpool.                       trioxide solutions, which help to   • Accelerating – Accelerators
           Now Leader’s clients include a long   increase the substrate surface, thus   removes excess stannous hydroxide
         list of major automotive manufacturers   enhancing liquid absorption.   from the part, and also prevents
         where chrome is becoming pervasive.  • Conditioning – An optional step   skip plating occurrence during the
         “Motorcycles love chrome,” says Rob   in the plating on plastic process,   plating on plastics process.
         Corazza, Plant Manager.
           The resins are important. A variety
         of resins are used for plating on plastic
         applications, although 90 percent of
         these applications are ABS, the Grand                                                     NEW
         View report says. It has an acryloni-
         trile-styrene matrix which is evenly     Coating Thickness Gages
         distributed with butadiene rubber,
         which leads to effective plating. The   2 models
         butadiene is etched out from the ma-  Ferrous for Steel
         trix, leaving microscopic holes that are   Combo for All Metals
         utilized as bonding sites by the plate.
         Other factors that have encouraged the     Fast, repeatable measurements
         large scale use of ABS are the ease of   (60+ readings per minute)
         molding, high metallic adhesion,        Ready to measure—no adjustment
         affordability and low coefficient of    required for most applications
         thermal expansion.                      Onscreen averaging for up to 99 readings
           Other resins that may be used for     Strong, wear-resistant, ruby-tipped probe
         the plating on plastic process include     Two year warranty on gage body AND probe
         PEI (polyetherimide), PBT (polybuty-
         lene terephthalate), LCP (liquid crys-
         tal polymer), PEEK (polyether ether   www.defelsko.com
         ketone), and  nylon/polyamide,
         among others.                           1-800-448-3835
           PEEK and polypropylene can only                                    simply
         be plated in a blended form, says
         Grand View, adding that ABS polycar-                                    measures
         bonate (ABS/PC) is expected to wit-
         ness solid demand in the plating on                            DeFelsko Corporation   Ogdensburg, New York USA
                                                                      Tel: +1-315-393-4450   Email: techsale@defelsko.com
         plastics market in the coming years.
         www.cfcm.ca                                      CAnADIAn FInISHInG & COATInGS MAnuFACTuRInG   31
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