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P. 45

NEW TECHNOLOGY

            Glow discharge
    Glow discharge is an independent electric discharge in a gas with cold electrodes at currents
    of 10-5 - 1.0 A and low pressure (5 • 10-2-103 Pa), which has a characteristic structure in the
    form of alternating luminous areas of different colors and different intensity of luminescence.
    Its distinctive feature is the existence of a layer near the cathode with a large positive space
    charge, a strong field at the surface and a significant drop in potential of 100 - 400 V and
    more. The glow discharge got its name from the presence of the so-called glow on one of the
    electrodes (cathode).
            One  of  the  applications of  the  glow  discharge  is the  technology  of  plasma  chemical-
    thermal treatment of metals, which are designed to increase the hardness, wear resistance,
    fatigue strength, scuff resistance, heat resistance and corrosion resistance due to saturation
    of the surface of the processed products with nitrogen, carbon, boron, cadmium and several
    elements  at the  same  time.  During  processing,  the  products  are  immersed  in the  plasma
    of a glow discharge that burns between the cathode (products) and the anode (walls of the
    vacuum chamber) and contains the necessary saturating element. Positively charged ions of
    the saturating element under the action of an electric field are accelerated towards the product,
    bombarded and penetrated into their surface layer. In this case, the energy of ions is thousands
    of times higher than the energy of atoms during gas chemical-thermal treatment. The heating
    temperature of products during processing is 300 - 600 °C.
                                                                              The most demanded process in the
                                                                      world is the process of plasma nitriding
                          Cooled vacuum                               (nitriding in a glow discharge, ion-plasma
                             chamber                                  nitriding, Fig.  3,  4).  Ammonia,  argon,
        Argon                                Т                        propane,  natural  gas,  etc.  are  used  as
       Ammonia                                                        working gases.  Regulation and  control
       Propane                               Р         Control block  of  the  technological  process  is fully
          Air
                                                                      automated and is carried out according
                                                                      to a given technological program.  An
                                                  U.I                 observation  window is mounted  in
                                                       Plasma source  the  water-cooled chamber  for  visual
                                                                      observation of the process.
                                                                              The     distinctive     characteristics
             Pump
           (res. up to                                                of  this  process  in  comparison  with gas
           -, 2 mbar)       Glow                Anode                 chemical thermal treatment are:
                          discharge                                   ● reduction of the processing time by 2
                                              Cathode
                                                                      - 5 times  due  to the higher  saturation
    Fig. 3. Plasma nitriding scheme
                                                                      rate;
                                                                      ●  efficiency  of the process by reducing
                                                                      the consumption of working gases by 20
                                                                      - 100 times;



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