Page 22 - Phytochemistry -1 (PG404) / Clinical Pharmacy 2nd level students ( 2019 )
P. 22

Clinical pharmacy PharmD program             Third level                        Phytochemistry-1 (PG-504)


                   one  or  more  uronic  acid  units  in  their  molecular  structure,  they  are

                   sometimes called derived carbohydrates.

                                                        A. Gums


                          Item        Gum acacia (gum           Gum tragacanth          Artificial gum
                                              Arabic)
                         Source               Natural                 Natural               Artificial
                        Solubility      Soluble (no gel        Insoluble (gel) :          Insoluble
                                            formation)               Bassorin            adhesive gel.
                       Aqueous             Levorotatory            levorotatory         dextrorotatorty
                         solution
                      Composition         - 1  Arabin:   Ca, K,     - 1  Tragacanthin    :     Dextrin
                                      Mg salts of arabic      water soluble          Incomplete starch
                                       acid.                    part.                  hydrolysis.

                                          - 2  Oxidase enzyme:      - 2  Bassorin:   poly   Its complete
                                      turns benzidine or      methoxylated           hydrolysis gives
                                      tr. Guaiacum into       acid, H₂O               glucose.
                                       blue.                    insoluble part.

                                                                   - 3  Galacto - uronic
                                                                acid.

                                                                   - 4  Pentosans,
                                                              mucilage and
                                                               starch.




                             Test             Gum acacia (gum             Gum tragacanth        Artificial
                                                      Arabic)                                       gum
                      Pentose test           +ve                          +ve                    -ve
                      Benzid./H₂O₂           Blue/  greenish blue         -ve                    -ve

                      I₂ test                Yellowish brown            Minute scatered        Reddish
                                                                        due to    blue points     brown
                                                                         starch
                      Pb(Ac)₂                No white precipitate         white precipitate    white
                                                                                                 precipitate


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