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The Chemistry and Fertility of Soils under Tropical Weeds   25



                              The concentrations of free ions are relatively low compared to that absorbed
                           by  plants.    The  concentrations  of  free  ions  are  even  lower  than  the  dissolved
                                                                                 2+
                           element in soil water.  For example, the concentration of free Zn  is 40% of the
                                                     2+
                           total dissolved Zn and that of Cu  is even lower about 2% of the total dissolved Cu
                                                             +
                                                         +
                                                                 2+
                                                                          2+
                           (Elliz and Knezek, 1982).  The free K , Na , Ca , and Mg  are higher, about 70 –
                           90% of the respective total dissolved elements.  However, the amounts supplied by
                           all dissolved nutrient elements are also relatively low and do not suffice the plant
                           requirement.




                                  Organics                                    Plants

                                    Minerals

                                      Adsorbed


                                     Complexes             Free Ions           Chelates


                                                                Leaching
                                     Precipitates
                                     (Sec. Minerals)




                             Fig. 2.2.  The relationships between the mechanisms controlling the concentrations of
                                      nutrient elements in soil water (Adapted from Salam, 2017).


                              Therefore, the rest of the nutrient elements must be supplied by other sources
                           of readily available nutrients and  slowly available nutrient elements that include
                           soil  organic  matters,  soil  secondary  minerals  (precipitates),  and  soil  primary
                           minerals  (Fig.  2.2).    Most  of  the  nutrient  elements  in  the  soil  environment  are
                           contained in the soil solids.  These nutrient elements are not  available or slowly
                           available  to  plants.    These  nutrient  elements  must  be  converted  into  readily
                           available forms before being available for plant absorption.  Releasing these slowly
                           available  nutrient  elements  enables  the  use  of  these  elements  by  plants  and
                           vegetation and allows them to get into nutrient element cycles.  The mechanisms
                                                          Abdul Kadir Salam and Nanik Sriyani  – 2019
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