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The Chemistry and Fertility of Soils under Tropical Weeds   31



                              Some factors clearly govern the process of the primary mineral weathering in
                           the  soil  environment  (Table  2.2)  the  most  important  of  which  are  soil  moisture
                           content and soil pH.  All of the chemical weathering listed in Table 2.4 shows the
                           importance of water molecule.  None of these reactions occur in the absence of
                           water.  As stated previously, Eq. 2.14 shows that the weathering of orthoclase is
                           speeded by the presence of water molecule.  Shown in Eq. 2.14 and Table 2.4, the
                                      +
                           presence of H  also speeds up the chemical weathering.  Lowering the soil pH may
                           surely increase the rate of soil mineral weathering.  The importance of soil pH in
                           mineral weathering is also previously shown in Table 1.3.
                              It is always true that the nutrient elements in soil water are not supplied only
                           by inorganic sources like soil primary and secondary minerals but also by organic
                           sources.    Soil  organic  matter  may  reach  the  amount  of  5%  in  mineral  soils  and
                           therefore  it  may  serve  significant  amounts  of  nutrient  elements  in  the  soil
                           environment particularly for such nutrient elements as N, S, and P.  The soil organic
                                                                                             +
                           matters may decompose and release these nutrient elements in  the forms of NH 4 ,
                              -   2-                        -        2-
                           NO 3 , SO 4 , and orthophosphates (H 2 PO 4  and HPO 4 ), respectively (Table 2.3 and
                           Table  2.4  and  Fig.  1.7,  Fig.  1.8,  and  Fig.  1.9).    These  nutrient  elements  may
                           compensate their depletion caused by plant root absorption or other mechanisms.
                              The decomposition of organic matters in the soil environment is controlled by
                           several important factors.  As shown by Eq. 1.4, the soil enzymatic activity and soil
                           moisture  are  the  two  most  important  factors.    The  rate  of  organic  matter
                           decomposition  is  positively  related  to  the  activity  of  soil  enzymes  such  as
                           phosphatases, proteases, and arylsulfatases and soil moisture content.  This means
                           that  the  release  of  the  organic  matter  structural  elements  can  be  speeded  by
                           increasing  the  soil  enzymatic  activities  and  soil  water  content.    The  absence  of
                           water may stop and the absence of soil enzymes may retard the soil organic matter
                           decomposition.  Gianfreda (2015) states that all processes and functions that occur
                           in  the  rhizosphere  are  dominated  by  the  activities  of  plant  roots,  rhizosphere
                           microorganisms and root-microorganism interactions, and enzymes are recognized
                           as main actors of all activities occurring in rhizosphere environments. In general,
                           rhizosphere  enzymes  show  higher  activities  than  those  in  bulk  soil  because  the
                           rhizosphere soil is richer in organic C substrates.  Enzymes produced and released
                           by roots alter the availability of nutrients in the rhizosphere through the hydrolysis
                           of C-substrates and organic forms of nutrients such as N, P and S.
                              In addition to soil enzymes and water, there are other factors controlling the
                           rate of organic matter decomposition i.e.  soil pH, soil temperature, and soil C/N
                           ratios.    Soil  enzymes  cause  a  direct  effect  while  soil  water,  soil  pH,  soil

                                                          Abdul Kadir Salam and Nanik Sriyani  – 2019
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