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determine what was causing this odd   By 1987, the mass of scientific      500
                        phenomenon, atmospheric chemists   evidence helped convince the world’s                        1987
                        Susan Solomon, James Anderson,     nations to agree on the Montreal        400                 2008
                        Crutzen, and others mounted expedi-  Protocol, which aimed to cut CFC
                        tions in 1986 and 1987 to analyze   production in half by 1998. Within     300
                        atmospheric gases using ground stations   two years, further scientific evidence   Ozone depletion potential  (kilotons/year)
                        and high-altitude balloons and aircraft.   and computer modeling showed that   200
                        From their data they figured out how the   more drastic measures were needed.   100
                        region’s polar stratospheric clouds and   In 1990, the Montreal Protocol was
                        circulating winds provide ideal conditions   strengthened to include a complete   0
                        for chlorine from CFCs and other chemi-  phaseout of CFCs by 2000, in the      N 2 O  Ozone-depleting
                        cals to set in motion the destruction of   first of several follow-up agreements.   substances being
                        massive amounts of ozone.          Today, amounts of ozone-depleting                  phased out
                                                                                              Figure 2 Since most ozone-depleting
                                                                                              substances were phased out begin-
                            350                                     September                 ning in 1987, nitrous oxide (N O; left
                          Ozone levels (Dobson units)  250  Farman                            depleting substance we emit. It has less
                                                                                                                    2
                                                                                              bar) has become the primary ozone-
                                                                    October
                            300
                                                                                              impact than CFCs and other halocar-
                                                                                              bons did in 1987 (full-bar values), but
                                                                                              more impact than any other substance
                            200
                                                                                              today (lower portion of bars). Adapted
                            150
                                                                                              oxide (N O): The dominant ozone-depleting
                                                                                                   2
                                            paper
                                                                                              substance emitted in the 21st century. Science
                            100             et al.                                            from Ravishankara, A.R., et al., 2009. Nitrous
                              1955    1965   1975    1985   1995    2005    2015              326: 123–125, Fig 1. Reprinted by permission of
                                                       Year                                   AAAS and the author.
                         (a) Monthly mean ozone levels at Halley, Antarctica

                            310                                                              substances in the stratosphere are
                                           Nimbus 7    Meteor 3   Earth probe
                                           TOMS        TOMS  NOAA 9  TOMS      OMI           beginning to level off.
                          Ozone (Dobson units)  290                                          research. In 2009, a team led by     CHAPTER 17 • AT m os PHER i C   sC i E n CE , Ai R  Qu A li T y,  A nd Poll u T i on Con TR ol
                                                                                                 As the ozone layer begins a long-
                            300
                                                           SBUV/2
                                                                                             term recovery, scientists continue their
                                                                                             A.R. Ravishankara of the National
                                                                                             Oceanic and Atmospheric Adminis-
                                  Farman
                            280
                                  et al.
                                                                                             (N O) had now become the leading
                                  paper                                                      tration determined that nitrous oxide
                                                                                               2
                                                                                             cause of ozone depletion (Figure 2).
                            270
                                1980     1985     1990     1995     2000      2005    2010   Its emissions are not regulated, so
                                                          Year                               its impacts have come to surpass
                                                                                             those that the remaining halocarbons
                         (b) Global ozone readings from 5 satellites
                                                                                             currently exert. Ravishankara’s team
                        Figure 1 Monitoring shows ozone depletion. Data from Halley, Antarctica (a), show a   points out that regulating nitrous
                        decrease in stratospheric ozone concentrations from the 1960s to 1990. Once ozone-  oxide, which is also a potent green-
                        depleting substances began to be phased out, ozone concentrations stopped declining.   house gas, would help mitigate cli-
                        Ozone decline and stabilization are also evident globally (b), as seen in data from five   mate change as well as speed ozone
                        satellites. Data from (a) British Antarctic Survey; and (b) NASA.    recovery.






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           M17_WITH7428_05_SE_C17.indd   489                                                                                    12/12/14   3:22 PM
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