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                                               Electron charge cloud
                                                                                E x









                          Nucleus




                                                                           x
                                        (a)                               (b)

                 Figure 10.1 Classical electron oscillator model: (a) in equilibrium; (b) in the presence of an external field.


            When an external electric field intensity E is applied to an atom, the electron charge cloud is displaced
                                               x
            from its equilibrium position, as shown in Fig. 10.1(b). The equation of motion for the center of the electron
            charge cloud is given by Newton’s law,

                                                  2
                                                 d x
                                               m    = F ext  = q E ,                          (10.1)
                                                             e x
                                                 dt 2
            where x(t) is the displacement of the center of the electron charge cloud, m is the electron mass, and q e
            is the electron charge. When the center of the electron cloud moves away from the equilibrium position
            (Fig. 10.1(b)), there is a force of attraction between the nucleus and the electron charge cloud. If the displace-
            ment x(t) is small, the restoration force can be approximated as

                                                F restoration  =−Kx,                          (10.2)

            where K is a constant. The negative sign indicates that the restoration force acts in a direction opposite to
            the external force. The situation is similar to the case of a simple pendulum pushed away from the equilib-
            rium position by an external force; there is a restoration force due to gravitation which pulls it back to the
            equilibrium position. The net force acting on the electron is given by

                                         F  = F   + F       = q E − Kx.                       (10.3)
                                          net   ext  restoration  e x
            Combining Eq. (10.3) with Newton’s law, we obtain
                                                2
                                               d x
                                             m    = F net  = q E − Kx                         (10.4)
                                                           e x
                                               dt 2
            or
                                                2
                                               d x   2   (  q e  )
                                                  +  x =    E ,                             (10.5)
                                                               x
                                                     0
                                               dt 2        m
            where  =(K∕m) 1∕2  is the natural frequency of oscillation. Suppose the applied field is of the form
                   0
                                                E = E exp (−it).                            (10.6)
                                                 x
                                                     0
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