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Nonlinear Effects in Fibers                                                        425


           at frequency 2 lead to the generation of an electromagnetic wave at 2. Crystals such as quarts have no center
           of symmetry and, therefore, they have a nonzero  (2)  coefficient. In the case of optical glass fibers, SiO 2
           (silica) is a symmetric molecule and  (2)  is zero. Therefore, second harmonic generation does not normally
           occur in optical fibers. The third-order susceptibility  (3)  is responsible for third harmonic generation and the
           Kerr effect.
            Suppose the incident electromagnetic field has only E and H components. For a centrally symmetric
                                                               y
                                                         x
           dielectric material, the tensor equation (10.41) can be simplified to obtain
                                                  (1)      (3)  3
                                           P =   E +    E ,                        (10.42)
                                            x   0 xx  x  0 xxxx x
                 (3)                                   (3)
           where  xxxx  is a component of the fourth-rank tensor  . Suppose the incident optical field is a monochro-
           matic wave,
                                              E = E exp (−it).                           (10.43)
                                               x   0
                  3
           To find E , as pointed out in Section 1.6.2, we should first take the real part of E ,
                                                                          x
                  x
                                           1               ∗
                                   Re[E ]= [E exp (−it)+ E exp (it)],                  (10.44)
                                       x      0            0
                                           2
                                           1   3             ∗3
                                        3
                                {Re[E ]} = {E exp (−3it)+ E exp (3it)
                                     x
                                              0
                                                             0
                                           8
                                                 2
                                                                 ∗
                                           + 3|E | [E exp (−it)+ E exp (it)]}.         (10.45)
                                               0
                                                    0
                                                                 0
           From Eqs. (10.42) and (10.45), we find that the incident field oscillating at frequency  leads to a component
           of polarization oscillating at frequency 3, which is responsible for third harmonic generation. The electro-
           magnetic wave at frequency 3 becomes significant only when special phase-matching techniques are used.
           Otherwise, the component of polarization at frequency 3 can be ignored. Hence, we ignore the first two
           terms on the right-hand side of Eq. (10.45).
            Let the polarization at frequency  be
                                        P = P exp (−it),                                 (10.46)
                                          x   0
                                             1               ∗
                                     Re[P ]= [P exp (−it)+ P exp (it)].                (10.47)
                                         x      0            0
                                             2
           From Eq. (10.42), we have
                                                (1)          (3)     3
                                     Re[P ]=   Re[E ]+    Re[E ] ,                 (10.48)
                                                      x
                                                           0 xxxx
                                              0 xx
                                                                   x
                                         x
           where the imaginary parts of the susceptibility are ignored. Substituting Eqs. (10.44) and (10.45) into
           Eq. (10.48), collecting the terms that are proportional to exp (−it), and comparing it with Eq. (10.47), we
           obtain                         (           2   )
                                                 3 E  |
                                                  |
                                             (1)        (3)
                                   P =      +  | 0|    E =   E ,                 (10.49)
                                     0   0   xx         xxxx  0   0 eff 0
                                                   4
           where   is the effective susceptibility that includes both linear and nonlinear susceptibilities. From Eq.
                 eff
                                                          (1)
                                                  2
           (10.29), in the absence of nonlinearity, we have n = 1 +  . Now, we modify it as
                                                          xx
                                                                2
                                                               0
                                       2                (1)  3|E |  (3)
                                      n = 1 +   = 1 +   +                            (10.50)
                                               eff     xx         xxxx
                                                              4
                                                   2
                                                     (3)
                                                  0
                                           2
                                         = n +  3|E |   xxxx ,                           (10.51)
                                           0     4
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