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CHAPTER 66
UNSTABLE (REACTIVE) MATERIALS
User note:
About this chapter: Chapter 66 addresses the hazards of unstable (reactive) liquid and solid materials as well as unstable (reactive) com-
pressed gases. In addition to their unstable reactivity, these materials may pose other hazards, such as toxicity, corrosivity, explosivity, flam-
mability or oxidizing potential. This chapter, however, is intended to address those materials whose primary hazard is unstable reactivity.
Materials that pose multiple hazards must conform to the requirements of the code with respect to all hazards. Strict compliance with the pro-
visions of this chapter, along with proper housekeeping and storage arrangements, helps to reduce the exposure hazards associated with
unstable (reactive) materials in a fire or other emergency.
SECTION 6601 6603.1.2 Limitations for indoor storage and use by
GENERAL occupancy. The indoor storage of unstable (reactive)
6601.1 Scope. The storage and use of unstable (reactive) materials shall be in accordance with Sections 6603.1.2.1
materials shall be in accordance with this chapter. Com- through 6603.1.2.5.
pressed gases shall also comply with Chapter 53. 6603.1.2.1 Group A, E, I or U occupancies. In Group
Exceptions: A, E, I or U occupancies, any amount of Class 3 and 4
unstable (reactive) materials shall be stored in accor-
1. Display and storage in Group M and storage in dance with the following:
Group S occupancies complying with Section
5003.11. 1. Class 3 and 4 unstable (reactive) materials shall
be stored in hazardous material storage cabinets
2. Detonable unstable (reactive) materials shall be complying with Section 5003.8.7.
stored in accordance with Chapter 56.
2. The hazardous material storage cabinets shall not
6601.2 Permits. Permits shall be required as set forth in Sec-
contain other storage.
tion 105.6.
6603.1.2.2 Group R occupancies. Class 3 and 4 unsta-
ble (reactive) materials shall not be stored or used
SECTION 6602 within Group R occupancies.
DEFINITION 6603.1.2.3 Group M occupancies. Class 4 unstable
6602.1 Definition. The following term is defined in Chapter (reactive) materials shall not be stored or used in retail
2: sales portions of Group M occupancies.
UNSTABLE (REACTIVE) MATERIAL. 6603.1.2.4 Offices. Class 3 and 4 unstable (reactive)
Class 4. materials shall not be stored or used in offices of Group
Class 3. B, F, M or S occupancies.
Class 2. 6603.1.2.5 Classrooms. In classrooms in Group B, F or
Class 1.
M occupancies, any amount of Class 3 and 4 unstable
(reactive) materials shall be stored in accordance with
SECTION 6603 the following:
GENERAL REQUIREMENTS 1. Class 3 and 4 unstable (reactive) materials shall
be stored in hazardous material storage cabinets
6603.1 Quantities not exceeding the maximum allowable
quantity per control area. Quantities of unstable (reactive) complying with Section 5003.8.7.
materials not exceeding the maximum allowable quantity per 2. The hazardous material storage cabinets shall not
control area shall be in accordance with Sections 6603.1.1 contain other storage.
through 6603.1.2.5.
6603.2 Quantities exceeding the maximum allowable
6603.1.1 General. The storage and use of unstable (reac- quantity per control area. The storage and use of unstable
tive) materials in amounts not exceeding the maximum (reactive) materials in amounts exceeding the maximum
allowable quantity per control area indicated in Section allowable quantity per control area indicated in Section
5003.1 shall be in accordance with Sections 5001, 5003, 5003.1 shall be in accordance with Chapter 50 and this chap-
6601 and 6603. ter.
2018 INTERNATIONAL FIRE CODE ® 497
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