Page 402 - Copper and Bronze in Art: Corrosion, Colorants, Getty Museum Conservation, By David Scott
P. 402

1.  Incralac
                2.  Sedonalacq  (an ethylene glycol  terephthalate)
                3.  benzotriazole
                4.  Butcher's  bowling-alley-paste wax  (carnauba  wax;  3 8  natural  and  synthetic  waxes in
                    mineral spirits, also known as white spirit; and turpentine or a substitute usually made
                    of  hydrocarbons)
                5.  National Park  Service wax mixture (82% Bareco Victory white microcrystalline wax;
                    15% Bareco 2000 polyethylene wax; and  3% Cosmoloid 80H microcrystalline wax with
                    3% benzotriazole  added)
                6.  Tatti wax mixture (85% Bareco Victory brown microcrystalline wax; 10% Bareco 2000
                    polyethylene wax; and  5% Cosmoloid 8OH microcrystalline wax)
                7.  no coating (controls)

                The  results  of this study  showed  that  the  Incralac-coated  panels,  both spray-  and  brush-
             coated specimens,  suffered some degradation during the sixteen weeks of exposure to both envi­
             ronments. There were no discernible differences  between the wax mixtures with  benzotriazole
             and those without. After sixteen weeks there was slightly more deterioration of the wax-coated
             samples exposed  to the  simulated acid rain  than  those exposed  outdoors. After  twenty-seven
             weeks of outdoor exposure,  the wax-coated samples showed more corrosion than the samples
             coated  with  the  acrylic materials. Many of the  acrylics, however,  had  a tendency  to  become
             detached  from  the substrate; delamination of the coating from the substrate around edges of the
             coupons  was a common problem.
                In  another  study, Weil  (1975) reported  that Incralac gave good protection as  a coating for
             outdoor bronzes  for at least two years; when the Incralac coating was protected with  a micro-
             crystalline wax  finish  that was periodically reapplied, it performed well for about  three  years.
             The  practical  difficulties  of maintaining Incralac  coatings  was  highlighted by  Erhardt  and
             coworkers (i984). They examined the ten-year-old Incralac surface  on four outdoor gold-plated
             bronze  statues in Washington, D.C., and  discovered it to  be  cracked  and  insoluble. Beale, 39
             however,  notes that two factors in connection with  these bronzes  were  not addressed in this
             study:  first, chemical residues were left on the surface  from  the on-site gold electroplating pro­
             cess used  on the  sculptures;  second,  the inappropriate  use  of Incralac over a highly reflective
             gilded surface contributed to this particular cross-linking of the Incralac polymer. These  surface
             conditions not only subjected  the coating to higher than normal temperatures  but  also nearly
             doubled the  dose of uv radiation. The Incralac was removed by softening with paint remover
             incorporating methylene  dichloride, followed by pressurized  water  spraying. Compared  with
             fresh Incralac, the uv absorption of the weathered material was greater, and most of the  benzo­
             triazole content had been depleted. Benzotriazole is often stated  as being added to this polymer






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