Page 29 - Analytical Chemistry I E-book
P. 29

Acid Base Equilibrium in water

   A weak acid only ionizes to a small extent and comes to a state
of chemical equilibrium.

    We can determine degree of ionization by calculating equilibrium

constant for this reaction, called ionization constant Ka.

  The larger (> 10-7) Ka , the more H+ are found in solution and the
stronger the acid and the reverse is true for the smaller Ka.

 HCOOH (aq) + H2O (l) < -- > H3O+ (aq) + HCOO- (aq)

 Ka = [H3O+][HCOO-]

              [HCOOH]
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