Page 498 - Applied Pharmacognosy
P. 498

Determination of chlorides
• Solution after combustion + ferric ammonium sulphate

  + mercuric thiocyanate and allow to stand for 10
  minutes.

• This method is based on the displacement of
  thiocyanate ion from mercuric thiocyanate by chloride
  ion, in the presence of ferric ion.

• A highly coloured ferric thiocyanate complex is formed.
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