Page 12 - ImmoCem-PCT-CE Geochem.pdf
P. 12

SEMI-DYNAMIC  MONOLITHIC TANK TESTING II-


            COMPARING RESULTS




                 Comparison of results from monolithic semi-dynamic tank testing with granular leaching for stabilised acid tars





                                                                      Max DOC from granular leaching

                                                                      following particle size reduction

                                                                            = 8100 mg/kg (48 hours)








                              Cummulative Leaching for Dissolved Organic Carbon(mg/l)                                             100  Cummulative Leaching for Dissolved Organic Carbon(mg/l)
                    Cummulative Leaching of Dissolved Organic  Carbon (mg/l)  70  DOC from monolithic leaching of            Cummulative Leaching of Dissolved Organic  Carbon (mg/kg)  80
                        90
                                                                                                                                  90
                        80
                                                                                                                                  70
                        60
                                                                                                                                  60
                                                                               stabilised waste form
                        50
                                                                                                                                  50
                        40
                                                                                                                                  40
                                                                            = 97.2 mg/kg (216 hours)
                        30
                                                                                                                                  30
                        20
                        10
                                                                                                                                  10
                         0
                           0     200     400    600    800    1000                                                                20 0  0   200   400    600    800    1000
                                                           1/2                                                                                                      1/2
                            Square Root of Cummulative Leaching Time (seconds )                                                      Square Root of Cummulative Leaching Time (seconds )
                   Using the derived effective diffusion rate up to F5(9 days) the estimated cumulative DOC
                                                                                                      2
                                                   leaching @ 64 days = 186 mg/kg (R  = 0.9997)
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