Page 23 - 2- WEKI Center - الايزو جزء الشرح

0.2 , 18.75 , 0.15 atm Cl2 ، PCl3 ، PCl5 

: 500 oK (٤)

PCl5(g) PCl3(g) + Cl2(g) -
‫ﺍﻟﺤــﻞ‬
Kp = (PPCl3) (PCl2) 18.75 x 0.2 = 25
(PPCl5) (٥)
=
0.15 ‫ﺍﻟﺤــﻞ‬

: 

PCl5(g) PCl3(g) + Cl2(g) Kp = 25 at 298 K
(٦)
: PCl3
 ‫ﺍﻟﺤــﻞ‬
0.48 atm Cl2 0.0021 atm PCl5

Kp = (PPCl3) (PCl2) 
(PPCl5)

(PPCl3) x 0.48

25 =
0.0021

(PPCl3) = 0.1094 atm

Br2(g) + H2(g) 2HBr(g)

-

1.5 atm ، 1 atm ، 0.5 atm

.

Kp = (PBr2) (PH2) (0.5) X (1)
(PHBr)2 = = 0.22

(1.5)2

١٤٩  

150