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Clinical pharmacy PharmD program                     Third level                          Phytochemistry-1 (PG-504)






                                                           1) Maltose = malt-sugar

              •  Is a reducing disaccharide formed from two units of glucose joined with an

                (1→4) linkage


              •  Chemically, it is 4-O-(-D-Glucopyranosyl)-D-glucopyranose.

              •  It does not occur free in nature. It occurs in germinating cereals as a result of

                amylase enzyme on starch.

              •  It is present as a component of polysaccharides such as starch, dextrin from

                which it is liberated as an end product of the action of amylase.













                                 4-O-( -D-glucopyranosyl)-D-glucopyranose


              Preparation:  It  is  prepared  from  starch  by  partial  hydrolysis  using  malt

                                                                                                     o
              (containing enzyme salivary amylase or pancreatic amylase, -Amylase) at 55 C.
              The  solution  is  boiled  to  coagulate  proteins,  filtered,  concentrated  and  left  to

              crystallize.



              Properties: Soluble in water.


              •  It is a reducing sugar having a potential aldehyde group:

                a)  Reduces  Fehling’s  solution,  undergoes  mutarotation  and  can  form

                   maltosazone (rosettes of plates or broad needles)

                b) Does not reduce Barfoed’s solution.

              Uses: Used as a nutrient (malt extract); and as a fermentative reagent



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