Page 258 - Natural Antioxidants, Applications in Foods of Animal Origin
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Methods and Their Applications for Measuring                   237
  VetBooks.ir  TABLE 6.6  (Continued)



                                   Fatty acid analysis (FAME)
                  Calculated derivative values for oxidative stability and nutritional value
                                   Fatty acid carbon notation
            % FA (normalized) C14:0  C16:0    C18:0 C18:1  C18:2  C18:3  Total
            FA distribution (mole fraction)
            Grass fed        7.3%   41.3%     22.0% 26.1%  1.90%  1.40% 100%
            Grain fed        12.9%  44.4%     8.90% 31.7%  1.90%  0.20% 100%

            Stability and    Calc. IV % IV (from  APE  BAPE  IT   AI    DFA/
            Nutritional value       C 18:3)                             OFA
            Grass fed        31.0   0.12%     62     5     0.47   1.06  1.53
            Grain fed        33.0   0.02%     72     2     1.84   2.38  0.62


            ratios are more favorable for grass fed beef. Similarly, IT and AI data (not
            shown) are more desirable for grass fed beef. Beef in the form of HOX
            MAPacked ground fresh beef offers consumers nutritional value, quality,
            and convenience they seek. However, HOX MAPackages have a finite shelf
            life because, during distribution and storage, meat becomes less red and
            lipid oxidation products increase. The relationship between TBARS and
            sensory (raw meat color) between raw HOX  (80% oxygen, 20% carbon dioxide)  MAPack-
            aged ground boneless forequarter meat from grain fed versus grass fed/
            grass finished beef.
               Color (CIE L*a*b*) and TBARS were used for both grass fed and grain
            fed MAPackaged raw, lean ground beef shelf-life study. Using both methods
            provided information about what consumers value most—color or flavor.
            The colorimetric data in the Figure 6.24 show grass fed beef; particularly
            grass fed beef with the incorporation of rosemary natural oxidation inhibitor
            is more color stable than grain fed beef.
               However, the TBARS data (Fig. 6.25) show the necessity of early addi-
            tion of an oxidation inhibitor (TBARS value at the “y” intercept for grass
            fed beef without an oxidation inhibitor at T = 0). The data also show it is the
            reactivity of the fatty acids not the fat content that is responsible for driving
            oxidation. Information from both methods provides the information needed
            to identify and address pre-emptively shelf-life challenges during the devel-
            opment of products from grass fed beef, for example, raw HOX MAPack-
            aged ground beef.
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