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234   Environmental Science and Technology | Progress Report




               Studies of trace gases and                     in	mid-2015.	An	ecological	survey	including
               greenhouse gases of urban                      a	biodiversity	assessment	has	been	conduct-

               areas and remote areas.                        ed	in	the	forest	region	surrounding	the	site.
                                                              Measurements	of	micrometeorological	and
                                                              atmospheric	chemical	variables	were	initiat-
               Modifications by Anthropogenic                 ed,	in	2012,	and	their	range	has	continued	to
               Pollution of the Natural Atmospheric           broaden	over	the	last	few	years.	The	meteo-
               Chemistry and Particle Microphysics            rological	and	micrometeorological	measure-
               of the Tropical Rain Forest During the         ments	include	temperature	and	wind	profiles,
               GoAmazon (Green Ocean Amazon).                 precipitation,	water	and	energy	fluxes,	turbu-

                                                              lence	components,	soil	temperature	profiles
               The	GoAmazon	campaign	seeks	to	quantify	       and	soil	heat	fluxes,	radiation	fluxes,	and	vis-
               and	understand	how	aerosol	and	cloud	life	cy-  ibility.	A	tree	has	been	instrumented	to	mea-
               cles	in	a	particularly	clean	background	in	the	  sure	stem	profiles	of	temperature,	light	inten-
               tropics	are	influenced	by	pollutant	outflow	   sity,	and	water	content	in	cryptogamic	covers.
               from	a	large	tropical	city,	all	in	the	context	of	  The	trace	gas	measurements	comprise	con-
               addressing	the	susceptibility	of	cloud-aero-   tinuous	monitoring	of	carbon	dioxide,	car-
               sol-precipitation	interactions	to	present-day	  bon	monoxide,	methane,	and	ozone	at	five	to
               and	future	pollution	in	the	tropics.	Within	   eight	different	heights,	complemented	by	a
               this	context	of	GoAmazon,	the	overall	goals	   variety	of	additional	species	measured	during
               of	the	proposed	research	are	(i)	to	measure	   intensive	campaigns	(e.g.,	VOC,	NO,	NO2,	and
               and	mechanistically	understand	the	factors	    OH	reactivity).	Aerosol	optical,	microphysi-
               affecting	the	number-diameter	distribution	    cal,	and	chemical	measurements	are	being
               n(d)	of	the	atmospheric	particle	population	   made	above	the	canopy	as	well	as	in	the	can-
               over	a	tropical	rain	forest	(especially	the	ef-  opy	space.	They	include	aerosol	light	scatter-
               fects	of	anthropogenic	pollution	as	a	pertur-  ing	and	absorption,	fluorescence,	number	and
               bation	to	natural	state)	and	(ii)	to	develop	and	  volume	size	distributions,	chemical	composi-
               implement	an	upscaling	analysis	from	this	     tion,	cloud	condensation	nuclei	(CCN)	concen-
               new	data	set	and	knowledge	of	n(d)	to	prog-    trations,	and	hygroscopicity.	In	this	paper,	we
               nosticate	possible	climatic	impacts	of	pres-   discuss	the	scientific	context	of	the	ATTO	ob-
               ent-day	urban	pollution	and	possibly	greater	  servatory	and	present	an	overview	of	results
               pollution	in	the	future.	                      from	ecological,	meteorological,	and	chemical
                                                              pilot	studies	at	the	ATTO	site.
               The Amazon Tall Tower Observatory
               (ATTO): overview of pilot measurements         Characterization of São Paulo
               on ecosystem ecology, meteorology,             contaminated areas by persistent organic
               trace gases, and aerosols.                     pollutants (POPs) and development
                                                              of a safe decomposition process.
               The	Amazon	Tall	Tower	Observatory	(ATTO)
               has	been	set	up	in	a	pristine	rain	forest	re-  Pesticides	banned,	obsolete	or	discarded	con-
               gion	in	the	central	Amazon	Basin,	about	150	   stitute	a	serious	environmental	risk	around	the
               km	northeast	of	the	city	of	Manaus.	Two	80m	   world,	especially	in	developing	countries.	Pes-
               towers	have	been	operated	at	the	site,	since	  ticides	are	among	the	compounds	that	consti-
               2012,	and	a	325m	tower	is	nearing	completion	  tute	the	group	of	so-called	POPs,	or	persistent





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