Page 302 - SUBSEC October 2017_Neat
P. 302

UNIT 1
               MODULE 3: CHEMISTRY OF THE ELEMENTS (cont’d)


                SPECIFIC OBJECTIVES                  EXPLANATORY NOTES           SUGGESTED PRACTICAL
                                                                                 ACTIVITIES

                First Row Transition Elements cont’d

                Students should be able to:

                5.3.     discuss  qualitatively  the   Melting   point,   density,
                         properties  of  transition   atomic   radius, ionic radius,
                         elements  when  compared    first  ionisation  energy  and
                         to  those  of  calcium  as  a   conductivity.
                         typical s-block element;
                  1.1
                5.4.   1.2   determine  the  electronic   Mention   changes   in
                         configuration  of  the  first   oxidation number.
                         row  transition  elements
                         and of their ions;

                5.5.   1.1   explain the relatively small
                         changes  in  atomic  radii,
                         ionic  radii  and  ionisation
                         energies  of  the  elements
                         across the period;

                5.6.   1.1   explain  the  formation  of   d-orbital   separation
                         coloured ions by transition   of  energy  in  octahedral
                         elements;                   complexes.

                5.7.   1.16   describe  the  variation  in   Refer to E  values.   Perform  experiments  to
                                                              θ
                         oxidation    states    of                                include  the  use  of  an
                         vanadium;                                                acidified   solution   of
                                                                                  ammonium  vanadate  (V)
                                                                                  and granulated zinc.

                5.8.     predict  the  shapes  of    Octahedral, tetrahedral and
                         complexes  of  transition   square planar.
                         elements;

                5.9.     discuss the use of:         Refer to Module 1, Specific
                         Fe 3+  (aq)/Fe 2+  (aq),    Objective 4.4.
                         MnO4(aq)/Mn 2+  (aq), and
                              2-
                         Cr2O7 (aq)/Cr 3+ (aq)  as  redox
                         systems; and,

                5.10.    explain  the  principle  of   Stability  constants  and  the   Perform  experiments  to
                         ligand exchange.            CO/O2 haemoglobin and        demonstrate        ligand
                                                     NH3(aq)/Cu 2+ (aq) systems.   exchange.        Include
                                                                                  reactions involving Co  2+  (aq),
                                                                                  Cu  2+ (aq).



                          CXC A11/U2/17                    33
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