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UNIT 1
               MODULE 3: CHEMISTRY OF THE ELEMENTS (cont’d)


                SPECIFIC OBJECTIVES                 EXPLANATORY NOTES          SUGGESTED  PRACTICAL
                                                                               ACTIVITIES

                6.        Identification of Cations and Anions

                Students should be able to:

                                           +
                                                +
                6.1.     identify  cations:  K ,  Na ,   Refer  to  atomic  emission   Perform  flame  tests  on
                                 2+
                            2+
                                       2+
                         Ca ,  Ba ,  Cu   by  their   spectra,  see  Module  1,   identified cations.
                         flame tests;                Specific Objective 1.7.

                6.2.     identify  cations  Mg 2+ (aq),   Include the reactions with   Perform experiments of the
                                                               2-
                                                        -
                         Al 3+ (aq),   Ca 2+ (aq),   Cr 3+ (aq),   OH (aq), CO 3(aq) and NH3(aq)   identified   cations   with
                         Mn 2+ (aq),  Fe 2+ (aq),  Fe 3+ (aq),   and confirmatory tests.   hydroxide  and  aqueous
                         Cu 2+ (aq),  Zn 2+ (aq),  Ba 2+ (aq),                  ammonia.

                                    +
                         Pb 2+ (aq), NH4 (aq);                                  Where  possible  perform
                                                                                confirmatory  tests  of  the
                                                                                identified cations.
                6.3.     explain the principles upon   Refer   to   equilibrium
                         which  the  reactions  in   concepts.   Module     2,
                         Specific  Objective  6.2  are   Specific Objective 5.2.
                         based;
                                                     Basic,  amphoteric  oxide
                                                     and complexation.

                6.4.     write  ionic  equations  for   Include state symbols.
                         the  reactions  in  Specific
                         Objective 6.2;

                6.5.     identify anions:            Include  the  reactions with   Perform  experiments  to
                                        2-
                                              2-
                                                                                                        2-
                             2-
                         CO3 ,  NO3’,  SO4 ,  SO3 (aq),   HCl(aq), conc H2SO4, Pb 2+ (aq),   identify  the  anions  CO3 ,
                                                                                              2-
                                                       +
                                                                                                       -
                           -
                               -
                                      2
                                                                                        2-
                                 -
                                                                                                    -
                         Cl , Br , l , CrO4 ; and,   Ag (aq), followed by NH3(aq),   NO3’, SO4 , SO3 (aq), Cl , Br , l -
                                                                                      2
                                                     Ca(OH)2(aq),      Ba 2+ (aq),   ,  CrO4 .  Where  applicable
                                                     followed  by  dilute  acid.    perform  confirmatory  tests
                                                     For   NO3’  use   copper   for gases.
                                                     turnings and conc H2SO4 or
                                                     add aluminium (powder) or
                                                     zinc  (powder)  in  the
                                                     alkaline   solution   and
                                                     confirmatory   tests   for
                                                     gases where applicable.

                6.6.     write  ionic  equations  for   Include state symbols.
                         the  reactions  in  Specific
                         Objective 6.5.



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