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UNIT 2
               MODULE 1: THE CHEMISTRY OF CARBON COMPOUNDS (cont’d)


                SPECIFIC OBJECTIVES                 EXPLANATORY NOTES            SUGGESTED PRACTICAL
                                                                                 ACTIVITIES

                Functional Group Analysis, Reactions and Mechanisms cont’d

                Students should be able to:

                2.5.     explain  the  steps  involved   Electrophilic  addition  of
                         in   the   mechanism   of   bromine    and   hydrogen
                         selected  chemical reactions   bromide to alkenes.
                         of alkene functional group;
                                                     Include   movement      of
                                                     electrons.  To  be  indicated

                                                     by  curved  arrows  and  fish
                                                     hook notation.

                2.6.     describe  selected  chemical   Reactions  of  alcohols  to   Perform   experiments
                         reactions of alcohols;      include  primary,  secondary   examining  the  fragrances
                                                                   0
                                                                              0
                                                                      0
                                                     and  tertiary  (1 ,  2 ,  and  3    produced  when  different
                                                     respectively)        with   esters are formed.
                                                                +
                                                     KMnO 4(aq) /H (aq)  purple  to
                                                     colourless with primary and
                                                     secondary; no reaction with
                                                     tertiary;
                                                                +
                                                     K 2Cr 2O 7(aq)/H (aq)  orange  to
                                                     green  with  primary  and
                                                     secondary; no reaction with
                                                     tertiary;
                                                     Carboxylic acid (R-COOH);
                                                     conc.  sulphuric  acid.  A
                                                     solution  of  I2  and  NaOH
                                                     (iodoform test).
                                                     Equations  for  reactions  of
                                                     alcohols with carboxylic acid
                                                     and conc. sulphuric acid only
                                                     are required.

                2.7.     describe  selected  reactions   Limited  to  hydrolysis  of
                         of halogenoalkanes;         primary    and     tertiary
                                                     halogenoalkanes      using
                                                     NaOH(aq).  (No  elimination
                                                     reaction required).









                          CXC A11/U2/17                    39
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