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stops any further diffusion of charge carriers. This initial diffusion of charge
carriers at the junction, and the development resultant barrier voltage take
place when a p–n junction is formed during the manufacturing process. The
barrier voltage depends upon the amount of doping, charge carriers, and the
junction temperature. For germanium the barrier voltage is 0.3 V and for
silicon the barrier voltage is 0.7 V at room temperature (25°C). The shaded
portion on both sides of the p–n junction is having only immobile ions of
opposite polarities which creates a potential difference, i.e., barrier voltage.
This portion is devoid of any electron or hole, i.e., any charge carriers. This
region is depleted of any charge carrier, and hence is called the depletion
region. It may be noted that the thickness of the depletion region in Fig. 14.5
(b) has been shown expanded. In fact, this layer is very thin, of the order of
micrometer.
The p-side of the depletion region acceptor impurity atoms that have lost
their holes associated with them by accepting electrons have become
negatively charged ions. Similarly the n-side of the depletion region consists
of donor atoms (pentavalent atoms) that have lost their associated free
electrons and have become positive ions. As shown in Fig. 14.5 (b), the
depletion layer is equally divided on both sides of the p–n junction. This is
because both the p-type and the n-type materials have been equally doped.
Equal percentage of doping materials have been added on both sides. If the
doping is different, the width of the depletion region on the two sides will be
different. Application of some voltage across the p–n junction is called
biasing. Depending on the polarity of biasing the width of the depletion layer
will change.
14.4.4 Biasing of p–n Junction
Biasing of a p–n junction means application of some external voltage across
the two sides of the p–n junction. When the p-side is connected to the
positive terminal of a battery and the n-side is connected to the negative
terminal, the p–n junction is said to be a forward-biased junction. If the
positive terminal of the battery is connected to the n-side and the negative

