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Lasers                                                                              99


           from collection of atoms is not perfectly monochromatic; this is because the emission can take place due to
           transition from any of the sublevels. The interaction of electromagnetic waves over a range of frequencies
           with the two-band system is described by a lineshape function l(). Out of N (or N ) atoms per unit volume,
                                                                       2
                                                                             1
           N l()d (or N l()d) atoms interact with electromagnetic waves in the frequency interval [,  + d].
                       1
            2
           The lineshape function is normalized such that
                                                 N l()d = N .                           (3.24)
                                              ∫   2         2
           In other words, N represents the total number of atoms per unit volume in band 2 and N l()d represents
                         2                                                        2
           the fraction of atoms per unit volume that could interact with radiation ranging from  to  + d. Therefore,
           the total stimulation rate per unit volume is

                                          R    =   Bu ()l()N d.                       (3.25)
                                            stim  ∫  s       2
           Similarly, the absorption rate per unit volume is modified as

                                           R abs  =  ∫  Bu ()l()N d.                  (3.26)
                                                     s
                                                             1
           Let us consider a special case in which the radiation is a monochromatic wave of frequency  . The energy
                                                                                      0
           spectral density per unit volume of a monochromatic wave is an impulse function given by
                                           u ()= u( −  )∕(2).                     (3.27)
                                            s
                                                          0
           Since the energy spectral density is energy per unit frequency interval, its integration over frequency is energy.
           Therefore,
                                       u ()d = u  ( −  )d∕(2)= u.             (3.28)
                                    ∫   s        ∫         0
           Here, u is energy per unit volume or energy density. Substituting Eq. (3.27) in Eqs. (3.25) and (3.26), we find
                                              R stim  = Bul( )N ,                         (3.29)
                                                            2
                                                         0
                                              R   = Bul( )N .                             (3.30)
                                                abs      0  1
           By letting Bl( ) → B, Eqs. (3.29) and (3.30) are the same as Eqs. (3.3) and (3.2), respectively, with the
                       0
           exception that u is replaced by energy density u.
                       s


           Example 3.1
           In an atomic sytem, the spontaneous lifetime associated with 2 → 1 transition is 2 ns and the energy difference
           between the levels is 2.4 × 10 −19  J. Calculate the Einstein A and B coefficients. Assume that the velocity of
                                    8
           light in the medium is 1.25 × 10 m∕s.
           Solution:
           From Eq. (3.23), we have
                                                  1        8 −1
                                            A  =    = 5 × 10 s .
                                             21
                                                 t
                                                  sp
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