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Lasers                                                                             111


           transition, while it increases due to absorption and external pumping. The net growth rate of the population
           density of state 2 is
                                     dN 2
                                         = R pump  + R abs  + R stim  + R spont  + R .      (3.70)
                                                                     nr
                                      dt
           Here, R abs , R stim , and R spont  are given by Eqs. (3.2), (3.3), and (3.4), respectively. R pump  refers to the pumping
           rate, which is the rate at which the population density of state 2 grows due to an external pump. A specific
           pumping scheme is discussed in Section 3.8.
            An atom in state 2 could drop down to state 1 by releasing the energy difference as translational, vibra-
           tional, or rotational energies of the atom or nearby atoms/molecules. This is known as non-radiative transition,
           since no photon is emitted as the atom makes transition from state 2 to state 1 and R represents the rate of
                                                                              nr
           non-radiative transition from state 2 to state 1. It is given by
                                                 R = CN ,                                   (3.71)
                                                  nr     2
           where C is a constant similar to the Einstein coefficient A.
            Using Eqs. (3.2), (3.3), (3.4), and (3.71) in Eq. (3.70), we find
                                    dN 2
                                        = R pump  + BuN − BuN −(A + C)N .                   (3.72)
                                                           2
                                                     1
                                                                      2
                                     dt
           The population density of the ground state increases due to stimulated emission, spontaneous emission, and
           non-radiative transition, while it decreases due to absorption. The rate of change of the population density of
           the ground state is
                                        dN 1
                                            = R stim  + R spont  + R + R abs
                                                            nr
                                         dt
                                            = BuN +(A + C)N − BuN .                         (3.73)
                                                 2
                                                            2
                                                                  1
            Next, let us consider the growth rate of photons. Let N ph  be the photon density. When an atom makes a
           transition from the excited state to the ground state due to stimulated emission, it emits a photon. If there are
           R stim  transitions per unit time per unit volume, the growth rate of photon density is also R stim . The photon
           density in a laser cavity increases due to stimulated emission and spontaneous emission, while it decreases
           due to absorption and loss in the cavity. The growth rate of photon density is given by

                                       dN
                                          ph
                                            = R stim  + R spont  + R abs  + R loss .        (3.74)
                                         dt
           Here, R loss  refers to the loss rate of photons due to internal loss and mirror loss in the cavity. Since the energy
           of a photon is ℏ, the mean number of photons present in the electromagnetic radiation of energy E is
                                                       E
                                                 n ph  =  .                                 (3.75)
                                                       ℏ
           The photon density N is the mean number of photons per unit volume and the energy density u is the energy
                            ph
           per unit volume. Therefore, they are related by
                                                 n ph  E      u
                                           N ph  =  =      =    .                           (3.76)
                                                 V    ℏV   ℏ
           In Section 3.3, we developed an expression for the time rate of change of the energy density u in the presence
           of stimulated emission and loss as
                                              du
                                                 =(G −  cav )u.                         (3.77)
                                              dt
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