Page 13 - E-LKM ACID BASE
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Lembar Kerja Mahasiswa - Asam Basa





                    When strong acids dissolve in water. The acid is entirely ionized or
             decomposed. For example, hydrochloric acid following:


                                                             +
                                                 HCl                      H          +   Cl -
                                                             (aq)
                                           (aq)
                                                                            (aq)
             Consider what happens when hydrogen chloride is mixed into water:
















                      Hydrogen  chloride  donates  a  hydrogen  ion  to  one  of  the
              nonbonding  electron  pairs  on  a  water  molecule,  resulting  in  a  third

              hydrogen  bonded  to  the  oxygen.  In  this  case,  hydrogen  chloride
              behaves  as  an  acid  (proton  donor)  and  water  behaves  as  a  base
              (proton  acceptor).  The  products  of  this  reaction  are  a  chloride  ion
                                                  +
              and  a  hydronium  ion,  H  O  ,  which,  as  Figure  7  shows,  is  made  by
                                              3
              adding a proton (hydrogen ion) to a water molecule.


                         A  strong  acid  has  a  weak  conjugate  base  and  vice  versa.  The
               extend to which a dissolved substance can act as an acid or a base
               depends  largely  on  the  solvent.  The  solute  only  shows  acidic

               properties  if  its  proton-donating  properties  exceed  those  of  the
               solvent, and HF is forced to act as a base in liquid HClO   as solvent
                                                                                       4





               Mineral acids in water as solvent all have a much stronger tendency

               to  dona  protons  than  does  water.  The  mineral  acids  all  donate
               protons to the water, and ionize completely.  Differentiating solvents
               such  as  glacial  acetic  acid  emphasize  the  difference  in  acidic
               strength,  and  sever  mineral  acids  are  only  partially  ionized  in  this
               solvent. This is because acele acid is a poor proton acceptor but a

               rather better proton donor. This behaviour also means that a solute
               which acts as a weak base in water behaves as strong base in acetic
               acid: the solvent thus exerts a levelling effect on bases.







           Bahasa Inggris Kimia (PKIM3139)                                                                        9
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