Page 29 - 01 PG Bab 01 Sifat Koligatif.pmd
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5. Jawaban: e                                     9. Jawaban: e
                           	  ‚    
ƒ                               ‹     ‹
                      –
                 mol e =                                             !    =   @*
                           	     !‡
                                  !     @*
                        = 0,01 mol
                 Reaksi elektrolisis larutan NaOH                  e  =       = 32
                                                                    Cu
                                        +
                                                 –
                          NaOH(aq) → Na (aq) + OH (aq)

                                             –
                                     –
                 Katode : 2H O( ) + 2e  → 2OH (aq) + H (g)         e Ni  =    = 29,5
                            2                        2
                              –
                                                 –
                 Anode : 4OH (aq) → 2H O( ) + 4e  + O (g)
                                        2             2             ‹ !
                                                                    
   =
                        –
                                    –
                 mol OH =   × mol e   =   × 0,01 mol = 0,01 mol

                                                                           ×

                                                                   W   =         = 1,28 gram
                                
                                    Cu
                                                   –3
                       –
                    [OH ]=         = 0,005 M = 5 × 10  M
                              *
                                                               10. Jawaban: a
                                     –3
                     pOH = –log 5 × 10
                                                                                 2+
                                                                                           2–
                                                                   MSO (aq) → M (aq) + SO (aq)
                         = 3 – log 5                                    4                  4
                                                                                     –
                                                                              2+
                      pH = 14 – pOH                                Katode  : M (aq) + 2e  → M(s)  +  –  ×2
                         = 14 – (3 – log 5)                        Anode   : 2H O( ) → O (g) + 4H (aq) + 4e  ×1
                                                                              2
                                                                                      2
                                                                            ––––––––––––––––––––––––––––––––––––––
                         = 11 + log 5                              Reaksi sel : 2M (aq) + 2H O( ) → 2M(s) + O (g) + 4H (aq)
                                                                                                          +
                                                                               2+
                                                                                       2            2
              6. Jawaban: a
                                                                   mol M =   $
                      ANa
                       r
                 e=                                                Pada proses penetralan:
                     valensi
                                                                         +
                                                                   mol H = mol OH –
                     23
                   =     = 23
                                                                              ×
                      1                                                  +
                                                                   mol H =         mol
                 i = 15 A
                 t = 50 menit = 50 × 60 detik                             = 0,01 mol
                       ××
                      ei t                                         mol M = 0,005 mol
                 W=
                      96.500                                               
    "
                                                                   A  M=
                               ×
                      23 15 50 60                                    r      
  "
                           ×
                        ×
                    =             gram
                         96.500
                                                                        =
              7. Jawaban: d
                                                                        = 24
                 W = 0,225 g
                                                               11. Jawaban: a
                                 $  ⋅⋅ *
                        ⋅⋅
                 W=    *     =                                     Reaksi elektrolisis larutan H SO  sebagai berikut.
                       	       	                                                           2   4
                                                                                                   2–
                                                                                          +
                                                                            H SO (aq) → 2H (aq) + SO (aq)
                                                                             2
                                                                                 4
                                                                                                   4
                              ⋅⋅ *                                            +        –
                 0,225 =   
   → i · t = 2.412,5 C                 Katode : 2H (aq) + 2e  → H (g)
                                                                                            2

                                                                                        +
                                                                                                 –
                                                                   Anode : 2H O( ) → 4H (aq) + 4e  + O (g)
                                                                              2                      2
              8. Jawaban: b                                                      
  Œ
                                                                   mol O =
                                                                         2
                        ⋅⋅

                        *                                                        <
 ‡
                 W =
                       	                                                           − 
  <
                                                                               ×
                                                                   mol O =
                                                                         2
                            $    ××                                               <
 ‡
                              *
                 mol × A =                                                          –3
                        r    	                                            = 6,25 × 10  mol

                                                                        –
                              *  ⋅                                 mol e =   × mol O
                     mol =                                                           2
                             ×

                                                                                        –3
                                                                          =   × 6,25 × 10 mol
                             ×
                      0,1 =   *
                             ×
                               	                                          = 2,5 × 10  mol
                                                                                   –2
                              ××
                        i=          	                              mol e –  = F
                                                                              ×
                                  
                                     –    *
                                                                   mol e =
                         = 10 ampere
                                                                                  ×

                                                                   2,5 × 10 –2  =

                                                                           t = 1.930 sekon
               28   Elektrolisis
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